Enhanced photocurrent production from thin films of Ru(II) metallopolymer/dawson polyoxotungstate adducts under visible irradiation

James J Walsh; Colm T Mallon; Alan Maxwell Bond; Tia E Keyes; Robert J Forster

doi:10.1039/c2cc17431f

Enhanced photocurrent production from thin films of Ru(II) metallopolymer/dawson polyoxotungstate adducts under visible irradiation

James J Walsh, Colm T Mallon, Alan Maxwell Bond, Tia E Keyes, Robert J Forster

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

53 Citations (Scopus)

Abstract

Thin films of polyoxometalates that are sensitized with a Ru(II) metallopolymer generate significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the photocurrent generated by the tungstate based adduct, alpha-[P2W18O62](6-), is approximately seven fold larger than that found for the Dawson polyoxomolybdate alpha-[S2Mo18O62](4-).

Original language	English
Pages (from-to)	3593 - 3595
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	30
DOIs	https://doi.org/10.1039/c2cc17431f
Publication status	Published - 2012

Access to Document

10.1039/c2cc17431f

Cite this

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title = "Enhanced photocurrent production from thin films of Ru(II) metallopolymer/dawson polyoxotungstate adducts under visible irradiation",

abstract = "Thin films of polyoxometalates that are sensitized with a Ru(II) metallopolymer generate significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the photocurrent generated by the tungstate based adduct, alpha-[P2W18O62](6-), is approximately seven fold larger than that found for the Dawson polyoxomolybdate alpha-[S2Mo18O62](4-).",

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journal = "Chemical Communications",

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T1 - Enhanced photocurrent production from thin films of Ru(II) metallopolymer/dawson polyoxotungstate adducts under visible irradiation

AU - Walsh, James J

AU - Mallon, Colm T

AU - Bond, Alan Maxwell

AU - Keyes, Tia E

AU - Forster, Robert J

PY - 2012

Y1 - 2012

N2 - Thin films of polyoxometalates that are sensitized with a Ru(II) metallopolymer generate significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the photocurrent generated by the tungstate based adduct, alpha-[P2W18O62](6-), is approximately seven fold larger than that found for the Dawson polyoxomolybdate alpha-[S2Mo18O62](4-).

AB - Thin films of polyoxometalates that are sensitized with a Ru(II) metallopolymer generate significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the photocurrent generated by the tungstate based adduct, alpha-[P2W18O62](6-), is approximately seven fold larger than that found for the Dawson polyoxomolybdate alpha-[S2Mo18O62](4-).

U2 - 10.1039/c2cc17431f

DO - 10.1039/c2cc17431f

M3 - Article

SN - 1359-7345

VL - 48

SP - 3593

EP - 3595

JO - Chemical Communications

JF - Chemical Communications

IS - 30

ER -