Enantioselective intramolecular 1,3-dipolar cycloadditions ofdiazocarbonyl-derived oxidopyryliums

David M. Hodgson, Paul A. Stupple, Craig Johnstone

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11 Citations (Scopus)

Abstract

Catalytic enantioselective tandem oxidopyrylium formation - intramolecular 1,3-dipolar cycloaddition reactions of phthalic anhydride-derived unsaturated diazocarbonyl compounds in up to 19% ee are described.

Original languageEnglish
Pages (from-to)49-58
Number of pages10
JournalARKIVOC
Volume2003
Issue number7
Publication statusPublished - 1 Dec 2003
Externally publishedYes

Keywords

  • Asymmetric catalysis
  • Cycloadditions
  • Diazo compounds
  • Oxidopyryliums
  • Rhodium

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