Elucidation of naphthalene diimide metallomacrocycles and catenanes by solvent dependent excimer and exciplex emission

Stephanie A. Boer; Rosalind P. Cox; Michael J. Beards; Huixin Wang; William A. Donald; Toby D.M. Bell; David R. Turner

doi:10.1039/c8cc09191a

Elucidation of naphthalene diimide metallomacrocycles and catenanes by solvent dependent excimer and exciplex emission

Stephanie A. Boer, Rosalind P. Cox, Michael J. Beards, Huixin Wang, William A. Donald, Toby D.M. Bell, David R. Turner

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

25 Citations (Scopus)

Abstract

Metallomacrocycles and [2]-catenanes based on a leucine substituted naphthalene diimide ligand have been confirmed in solution through detection of excimer and exciplex emission. Comparison with the behaviour of the free ligand provides insight into the solution speciation of the metallosupramolecular complexes and their solvent dependent nature.

Original language	English
Pages (from-to)	663-666
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	5
DOIs	https://doi.org/10.1039/c8cc09191a
Publication status	Published - 1 Jan 2019

Keywords

Rotaxanes
molecular shuttle
Crown ethers

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abstract = "Metallomacrocycles and [2]-catenanes based on a leucine substituted naphthalene diimide ligand have been confirmed in solution through detection of excimer and exciplex emission. Comparison with the behaviour of the free ligand provides insight into the solution speciation of the metallosupramolecular complexes and their solvent dependent nature.",

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author = "Boer, {Stephanie A.} and Cox, {Rosalind P.} and Beards, {Michael J.} and Huixin Wang and Donald, {William A.} and Bell, {Toby D.M.} and Turner, {David R.}",

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AU - Boer, Stephanie A.

AU - Cox, Rosalind P.

AU - Beards, Michael J.

AU - Wang, Huixin

AU - Donald, William A.

AU - Bell, Toby D.M.

AU - Turner, David R.

PY - 2019/1/1

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N2 - Metallomacrocycles and [2]-catenanes based on a leucine substituted naphthalene diimide ligand have been confirmed in solution through detection of excimer and exciplex emission. Comparison with the behaviour of the free ligand provides insight into the solution speciation of the metallosupramolecular complexes and their solvent dependent nature.

AB - Metallomacrocycles and [2]-catenanes based on a leucine substituted naphthalene diimide ligand have been confirmed in solution through detection of excimer and exciplex emission. Comparison with the behaviour of the free ligand provides insight into the solution speciation of the metallosupramolecular complexes and their solvent dependent nature.

KW - Rotaxanes

KW - molecular shuttle

KW - Crown ethers

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JO - Chemical Communications

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ER -

Elucidation of naphthalene diimide metallomacrocycles and catenanes by solvent dependent excimer and exciplex emission

Abstract

Keywords

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