Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide

H. B. Henbest; W. R. Jackson; B. C G Robb

doi:10.1039/J29660000803

Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide

H. B. Henbest, W. R. Jackson, B. C G Robb

Research output: Contribution to journal › Article › Research › peer-review

51 Citations (Scopus)

Abstract

The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0.65 for the permanganate reactions in aqueous dioxan and -0.55 for the osmium tetroxide reactions in dioxan.

Original language	English
Pages (from-to)	803-807
Number of pages	5
Journal	Journal of the Chemical Society B: Physical Organic
DOIs	https://doi.org/10.1039/J29660000803
Publication status	Published - 1 Dec 1966
Externally published	Yes

Access to Document

10.1039/J29660000803

Cite this

@article{5ef596ac9a0a452587d1f24852777215,

title = "Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide",

abstract = "The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0.65 for the permanganate reactions in aqueous dioxan and -0.55 for the osmium tetroxide reactions in dioxan.",

author = "Henbest, \{H. B.\} and Jackson, \{W. R.\} and Robb, \{B. C G\}",

year = "1966",

month = dec,

day = "1",

doi = "10.1039/J29660000803",

language = "English",

pages = "803--807",

journal = "Journal of the Chemical Society B: Physical Organic",

issn = "0045-6470",

publisher = "The Royal Society of Chemistry",

}

TY - JOUR

T1 - Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide

AU - Henbest, H. B.

AU - Jackson, W. R.

AU - Robb, B. C G

PY - 1966/12/1

Y1 - 1966/12/1

N2 - The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0.65 for the permanganate reactions in aqueous dioxan and -0.55 for the osmium tetroxide reactions in dioxan.

AB - The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0.65 for the permanganate reactions in aqueous dioxan and -0.55 for the osmium tetroxide reactions in dioxan.

UR - https://www.scopus.com/pages/publications/37049120528

U2 - 10.1039/J29660000803

DO - 10.1039/J29660000803

M3 - Article

AN - SCOPUS:37049120528

SN - 0045-6470

SP - 803

EP - 807

JO - Journal of the Chemical Society B: Physical Organic

JF - Journal of the Chemical Society B: Physical Organic

ER -

Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide

Abstract

Access to Document

Other files and links

Cite this