Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide

H. B. Henbest; W. R. Jackson; B. C G Robb

doi:10.1039/J29660000803

Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide

H. B. Henbest, W. R. Jackson, B. C G Robb

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0.65 for the permanganate reactions in aqueous dioxan and -0.55 for the osmium tetroxide reactions in dioxan.

Original language	English
Pages (from-to)	803-807
Number of pages	5
Journal	Journal of the Chemical Society B: Physical Organic
DOIs	https://doi.org/10.1039/J29660000803
Publication status	Published - 1 Dec 1966
Externally published	Yes

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title = "Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide",

abstract = "The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0.65 for the permanganate reactions in aqueous dioxan and -0.55 for the osmium tetroxide reactions in dioxan.",

author = "Henbest, {H. B.} and Jackson, {W. R.} and Robb, {B. C G}",

year = "1966",

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doi = "10.1039/J29660000803",

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journal = "Journal of the Chemical Society B: Physical Organic",

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T1 - Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide

AU - Henbest, H. B.

AU - Jackson, W. R.

AU - Robb, B. C G

PY - 1966/12/1

Y1 - 1966/12/1

N2 - The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0.65 for the permanganate reactions in aqueous dioxan and -0.55 for the osmium tetroxide reactions in dioxan.

AB - The oxidation of olefins (alicyclic compounds and stilbenes) by permanganate ion is accelerated by electron-attracting substituents, but these groups retard the reactions of the olefins with osmium tetroxide. For the stibene oxidations, approximate ρ values obtained were: 0.65 for the permanganate reactions in aqueous dioxan and -0.55 for the osmium tetroxide reactions in dioxan.

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JO - Journal of the Chemical Society B: Physical Organic

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ER -

Electronic effects in the reactions of olefins with permanganate ion and with osmium tetroxide

Abstract

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