Electronic Delocalization in Two and Three Dimensions: Differential Aggregation in Indium “Metalloid” Clusters

Andrey V. Protchenko, Juan Urbano, Joseph A.B. Abdalla, Jesús Campos, Dragoslav Vidovic, Andrew D. Schwarz, Matthew P. Blake, Philip Mountford, Cameron Jones, Simon Aldridge

Research output: Contribution to journalArticleResearchpeer-review

17 Citations (Scopus)

Abstract

Reduction of indium boryl precursors to give two- and three-dimensional M−M bonded networks is influenced by the choice of supporting ligand. While the unprecedented nanoscale cluster [In68(boryl)12] (with an In12@In44@In12(boryl)12 concentric structure), can be isolated from the potassium reduction of a bis(boryl)indium(III) chloride precursor, analogous reduction of the corresponding (benzamidinate)InIIIBr(boryl) system gives a near-planar (and weakly aromatic) tetranuclear [In4(boryl)4]2− system.

Original languageEnglish
Pages (from-to)15098-15102
Number of pages5
JournalAngewandte Chemie - International Edition
Volume56
Issue number47
DOIs
Publication statusPublished - 20 Nov 2017

Keywords

  • boryl
  • gallium
  • Group 13 elements
  • indium
  • metal cluster

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