Electrochemistry of Cyanocopper Thiomolybdates and Thiotungstates: Redox-Based Interconversion of Species

Michael Kony; Anthony G. Wedd; Alan M. Bond

doi:10.1021/ic00347a038

Electrochemistry of Cyanocopper Thiomolybdates and Thiotungstates: Redox-Based Interconversion of Species

Michael Kony, Anthony G. Wedd, Alan M. Bond

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

8 Citations (Scopus)

Abstract

[MoS₄]₂and its 1:1 and 1:2 CuCN adducts [(CN)CuS₂MoS₂]₂₋and [(CN)CuS₂MoS₂Cu(CN)]₂₋each exhibit electrochemically reversible one-electron reductions in MeCN at fast scan rates (>500 mV s₋₁). At lower scan rates, the reduced adduct species are unstable to dissociation of CuCN, leading to interconversion of the three anions. The tungsten analogues show similar properties.

Original language	English
Pages (from-to)	4521-4525
Number of pages	5
Journal	Inorganic Chemistry
Volume	29
Issue number	22
DOIs	https://doi.org/10.1021/ic00347a038
Publication status	Published - 1 Jan 1990

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title = "Electrochemistry of Cyanocopper Thiomolybdates and Thiotungstates: Redox-Based Interconversion of Species",

abstract = "[MoS4]2and its 1:1 and 1:2 CuCN adducts [(CN)CuS2MoS2]2−and [(CN)CuS2MoS2Cu(CN)]2−each exhibit electrochemically reversible one-electron reductions in MeCN at fast scan rates (>500 mV s−1). At lower scan rates, the reduced adduct species are unstable to dissociation of CuCN, leading to interconversion of the three anions. The tungsten analogues show similar properties.",

author = "Michael Kony and Wedd, {Anthony G.} and Bond, {Alan M.}",

year = "1990",

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journal = "Inorganic Chemistry",

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T1 - Electrochemistry of Cyanocopper Thiomolybdates and Thiotungstates

T2 - Redox-Based Interconversion of Species

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AU - Wedd, Anthony G.

AU - Bond, Alan M.

PY - 1990/1/1

Y1 - 1990/1/1

N2 - [MoS4]2and its 1:1 and 1:2 CuCN adducts [(CN)CuS2MoS2]2−and [(CN)CuS2MoS2Cu(CN)]2−each exhibit electrochemically reversible one-electron reductions in MeCN at fast scan rates (>500 mV s−1). At lower scan rates, the reduced adduct species are unstable to dissociation of CuCN, leading to interconversion of the three anions. The tungsten analogues show similar properties.

AB - [MoS4]2and its 1:1 and 1:2 CuCN adducts [(CN)CuS2MoS2]2−and [(CN)CuS2MoS2Cu(CN)]2−each exhibit electrochemically reversible one-electron reductions in MeCN at fast scan rates (>500 mV s−1). At lower scan rates, the reduced adduct species are unstable to dissociation of CuCN, leading to interconversion of the three anions. The tungsten analogues show similar properties.

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ER -

Electrochemistry of Cyanocopper Thiomolybdates and Thiotungstates: Redox-Based Interconversion of Species

Abstract

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