Electrochemical reduction of CO2 on core-shell Cu/Au nanostructure arrays for syngas production

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Electrocatalytically converting CO2 to hydrocarbons is a very attractive way to use the excess electricity generated from renewable energies. In this paper, we report the electrochemical reduction of CO2 based on Cu nanowire arrays. The Cu nanostructured electrode shows much higher current density than polycrystalline Cu. By sputter coating a thin layer of Au on the Cu nanowires, the Faradaic efficiency (FE) of CO can exceed 30%. At an overpotential of 540 mV with respect to the formation of CO, the Cu/Au core-shell nanowire array electrode catalyses the formation of syngas, a very useful gas mixture, with a stable CO/H2 ratio.

Original languageEnglish
Pages (from-to)84-89
Number of pages6
JournalElectrochimica Acta
Volume239
DOIs
Publication statusPublished - 10 Jun 2017

Keywords

  • CO reduction
  • core-shell Cu/Au nanostructures
  • faradaic efficiency
  • syngas

Cite this

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title = "Electrochemical reduction of CO2 on core-shell Cu/Au nanostructure arrays for syngas production",
abstract = "Electrocatalytically converting CO2 to hydrocarbons is a very attractive way to use the excess electricity generated from renewable energies. In this paper, we report the electrochemical reduction of CO2 based on Cu nanowire arrays. The Cu nanostructured electrode shows much higher current density than polycrystalline Cu. By sputter coating a thin layer of Au on the Cu nanowires, the Faradaic efficiency (FE) of CO can exceed 30{\%}. At an overpotential of 540 mV with respect to the formation of CO, the Cu/Au core-shell nanowire array electrode catalyses the formation of syngas, a very useful gas mixture, with a stable CO/H2 ratio.",
keywords = "CO reduction, core-shell Cu/Au nanostructures, faradaic efficiency, syngas",
author = "Kun Chen and Xinyi Zhang and Tim Williams and Laure Bourgeois and MacFarlane, {Douglas R.}",
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Electrochemical reduction of CO2 on core-shell Cu/Au nanostructure arrays for syngas production. / Chen, Kun; Zhang, Xinyi; Williams, Tim; Bourgeois, Laure; MacFarlane, Douglas R.

In: Electrochimica Acta, Vol. 239, 10.06.2017, p. 84-89.

Research output: Contribution to journalArticleResearchpeer-review

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AU - Zhang, Xinyi

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AB - Electrocatalytically converting CO2 to hydrocarbons is a very attractive way to use the excess electricity generated from renewable energies. In this paper, we report the electrochemical reduction of CO2 based on Cu nanowire arrays. The Cu nanostructured electrode shows much higher current density than polycrystalline Cu. By sputter coating a thin layer of Au on the Cu nanowires, the Faradaic efficiency (FE) of CO can exceed 30%. At an overpotential of 540 mV with respect to the formation of CO, the Cu/Au core-shell nanowire array electrode catalyses the formation of syngas, a very useful gas mixture, with a stable CO/H2 ratio.

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