Electrocarboxylation in ionic liquids

Shu Feng Zhao, Michael D. Horne, Alan M. Bond, Jie Zhang

Research output: Chapter in Book/Report/Conference proceedingChapter (Book)Researchpeer-review

Abstract

Four drivers have stimulated recent research into the electrochemical conversion of carbon dioxide into fuels and chemicals. (1) The prospect of using gaseous CO2, a gas previously considered a useless waste product, as an economical and abundant source of carbon. (2) The urgent need for effective energy storage technology. (3) The versatility of electrochemical methods. (4) Concern about the rising levels of CO2 in the atmosphere. Within this thriving research field, one area that has received significant attention and provides the focus of this review is the electrocarboxylation of organic compounds. Electrocarboxylation occurs when a reactive radical anion generated electrochemically from an organic substrate (or CO2) reacts with CO2 (or an organic substrate) to form a carboxylate. However, the high reactivity of the electrogenerated reactant means many factors can influence the reaction pathway, particularly the nature of the solvent and electrode. Special attention is given in this review to the use of ionic liquids in electrocarboxylation because these neoteric solvents provide promising alternatives to organic molecular solvents. Finally, some perspectives on potential industrial application of ionic liquids in electrocarboxylation are provided.

Original languageEnglish
Title of host publicationElectrochemical Reduction of Carbon Dioxide
Subtitle of host publicationOvercoming the Limitations of Photosynthesis
EditorsFrank Marken, David Fermin
Place of PublicationCroydon UK
PublisherThe Royal Society of Chemistry
Chapter7
Pages160-181
Number of pages22
Edition1st
ISBN (Electronic)9781782623809, 9781788014526
ISBN (Print)9781782620426
DOIs
Publication statusPublished - 2018

Publication series

NameEnergy and Environment Series
Number21
ISSN (Print)2044-0774
ISSN (Electronic)2044-0782

Cite this

Zhao, S. F., Horne, M. D., Bond, A. M., & Zhang, J. (2018). Electrocarboxylation in ionic liquids. In F. Marken, & D. Fermin (Eds.), Electrochemical Reduction of Carbon Dioxide: Overcoming the Limitations of Photosynthesis (1st ed., pp. 160-181). (Energy and Environment Series; No. 21). Croydon UK: The Royal Society of Chemistry. https://doi.org/10.1039/9781782623809-00160
Zhao, Shu Feng ; Horne, Michael D. ; Bond, Alan M. ; Zhang, Jie. / Electrocarboxylation in ionic liquids. Electrochemical Reduction of Carbon Dioxide: Overcoming the Limitations of Photosynthesis. editor / Frank Marken ; David Fermin. 1st. ed. Croydon UK : The Royal Society of Chemistry, 2018. pp. 160-181 (Energy and Environment Series; 21).
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Zhao, SF, Horne, MD, Bond, AM & Zhang, J 2018, Electrocarboxylation in ionic liquids. in F Marken & D Fermin (eds), Electrochemical Reduction of Carbon Dioxide: Overcoming the Limitations of Photosynthesis. 1st edn, Energy and Environment Series, no. 21, The Royal Society of Chemistry, Croydon UK, pp. 160-181. https://doi.org/10.1039/9781782623809-00160

Electrocarboxylation in ionic liquids. / Zhao, Shu Feng; Horne, Michael D.; Bond, Alan M.; Zhang, Jie.

Electrochemical Reduction of Carbon Dioxide: Overcoming the Limitations of Photosynthesis. ed. / Frank Marken; David Fermin. 1st. ed. Croydon UK : The Royal Society of Chemistry, 2018. p. 160-181 (Energy and Environment Series; No. 21).

Research output: Chapter in Book/Report/Conference proceedingChapter (Book)Researchpeer-review

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AB - Four drivers have stimulated recent research into the electrochemical conversion of carbon dioxide into fuels and chemicals. (1) The prospect of using gaseous CO2, a gas previously considered a useless waste product, as an economical and abundant source of carbon. (2) The urgent need for effective energy storage technology. (3) The versatility of electrochemical methods. (4) Concern about the rising levels of CO2 in the atmosphere. Within this thriving research field, one area that has received significant attention and provides the focus of this review is the electrocarboxylation of organic compounds. Electrocarboxylation occurs when a reactive radical anion generated electrochemically from an organic substrate (or CO2) reacts with CO2 (or an organic substrate) to form a carboxylate. However, the high reactivity of the electrogenerated reactant means many factors can influence the reaction pathway, particularly the nature of the solvent and electrode. Special attention is given in this review to the use of ionic liquids in electrocarboxylation because these neoteric solvents provide promising alternatives to organic molecular solvents. Finally, some perspectives on potential industrial application of ionic liquids in electrocarboxylation are provided.

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Zhao SF, Horne MD, Bond AM, Zhang J. Electrocarboxylation in ionic liquids. In Marken F, Fermin D, editors, Electrochemical Reduction of Carbon Dioxide: Overcoming the Limitations of Photosynthesis. 1st ed. Croydon UK: The Royal Society of Chemistry. 2018. p. 160-181. (Energy and Environment Series; 21). https://doi.org/10.1039/9781782623809-00160