Efficient photoinduced electron transfer in a rigid U-shaped tetrad bearing terminal porphyrin and viologen units

Katrina A. Jolliffe; Toby D.M. Bell; Kenneth P. Ghiggino; Steven J. Langford; Michael N. Paddon-Row

Efficient photoinduced electron transfer in a rigid U-shaped tetrad bearing terminal porphyrin and viologen units

Katrina A. Jolliffe, Toby D.M. Bell, Kenneth P. Ghiggino, Steven J. Langford, Michael N. Paddon-Row

Research output: Contribution to journal › Article › Research › peer-review

Abstract

Apparently solvent-mediated and not throughbond photoinduced electron transfer (ET) takes place from the porphyrin (P) unit to the methylviologen (MV²⁺) unit in the rigid U-shaped molecules 1 (i.e., k(TS)/(ET) > k(TB)/(ET); TS = through-solvent, TB = through-bond). The ratio of the rates of charge separation to charge recombination is greater than 1400:1.

Original language	English
Pages (from-to)	916-919
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	37
Issue number	7
Publication status	Published - 1 Jan 1998
Externally published	Yes

Keywords

Cycloadditions
Electron transfer
Isomerism
Porphyrinoids
Superexchange

Cite this

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abstract = "Apparently solvent-mediated and not throughbond photoinduced electron transfer (ET) takes place from the porphyrin (P) unit to the methylviologen (MV2+) unit in the rigid U-shaped molecules 1 (i.e., k(TS)/(ET) > k(TB)/(ET); TS = through-solvent, TB = through-bond). The ratio of the rates of charge separation to charge recombination is greater than 1400:1.",

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AU - Jolliffe, Katrina A.

AU - Bell, Toby D.M.

AU - Ghiggino, Kenneth P.

AU - Langford, Steven J.

AU - Paddon-Row, Michael N.

PY - 1998/1/1

Y1 - 1998/1/1

N2 - Apparently solvent-mediated and not throughbond photoinduced electron transfer (ET) takes place from the porphyrin (P) unit to the methylviologen (MV2+) unit in the rigid U-shaped molecules 1 (i.e., k(TS)/(ET) > k(TB)/(ET); TS = through-solvent, TB = through-bond). The ratio of the rates of charge separation to charge recombination is greater than 1400:1.

AB - Apparently solvent-mediated and not throughbond photoinduced electron transfer (ET) takes place from the porphyrin (P) unit to the methylviologen (MV2+) unit in the rigid U-shaped molecules 1 (i.e., k(TS)/(ET) > k(TB)/(ET); TS = through-solvent, TB = through-bond). The ratio of the rates of charge separation to charge recombination is greater than 1400:1.

KW - Cycloadditions

KW - Electron transfer

KW - Isomerism

KW - Porphyrinoids

KW - Superexchange

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IS - 7

ER -

Efficient photoinduced electron transfer in a rigid U-shaped tetrad bearing terminal porphyrin and viologen units

Abstract

Keywords

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