Efficient permeance recovery of organically fouled graphene oxide membranes

Sally El Meragawi, Abozar Akbari, Sebastian Hernandez, Akshat Tanksale, Mainak Majumder

Research output: Contribution to journalArticleResearchpeer-review

Abstract

The emergence of facile approaches for the large-scale production of graphene oxide (GO) membranes necessitates a clearer understanding of their potential to foul and, more importantly, strategies for efficient recovery of membrane performance following fouling. Here, we systematically investigated the feasibility of water, ethanol, and hypochlorite as cleaning agents to remove organic foulants over a GO membrane. Among them, 100 ppm hypochlorite solution showed a remarkable ability to remove bovine serum albumin (BSA) and could recover the membrane flux up to 98% after five cycles of BSA filtration and cleaning. The potential of hypochlorite was also demonstrated for permeance recovery during molecular filtration of tannic acid and methyl blue. Scanning electron microscopy, attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), and X-ray diffraction (XRD) analyses were used to study the oxidative effects of hypochlorite on the GO membrane, and it was determined that exposure to higher concentrations of hypochlorite (>1000 ppm) degrades the structure of GO membrane and deteriorates the membrane performance after three cycles of cleaning. The studies demonstrate that the use of a modest concentration of hypochlorite is effective in restoring permeance of this class of high flux nanofiltration membranes.
Original languageEnglish
Pages (from-to)584-592
Number of pages9
JournalACS Applied Bio Materials
Volume3
Issue number1
DOIs
Publication statusPublished - 21 Jan 2020

Keywords

  • flux recovery
  • fouling
  • graphene oxide
  • hypochlorite
  • membrane
  • nanofiltration

Cite this

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title = "Efficient permeance recovery of organically fouled graphene oxide membranes",
abstract = "The emergence of facile approaches for the large-scale production of graphene oxide (GO) membranes necessitates a clearer understanding of their potential to foul and, more importantly, strategies for efficient recovery of membrane performance following fouling. Here, we systematically investigated the feasibility of water, ethanol, and hypochlorite as cleaning agents to remove organic foulants over a GO membrane. Among them, 100 ppm hypochlorite solution showed a remarkable ability to remove bovine serum albumin (BSA) and could recover the membrane flux up to 98{\%} after five cycles of BSA filtration and cleaning. The potential of hypochlorite was also demonstrated for permeance recovery during molecular filtration of tannic acid and methyl blue. Scanning electron microscopy, attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), and X-ray diffraction (XRD) analyses were used to study the oxidative effects of hypochlorite on the GO membrane, and it was determined that exposure to higher concentrations of hypochlorite (>1000 ppm) degrades the structure of GO membrane and deteriorates the membrane performance after three cycles of cleaning. The studies demonstrate that the use of a modest concentration of hypochlorite is effective in restoring permeance of this class of high flux nanofiltration membranes.",
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Efficient permeance recovery of organically fouled graphene oxide membranes. / El Meragawi, Sally; Akbari, Abozar; Hernandez, Sebastian; Tanksale, Akshat; Majumder, Mainak.

In: ACS Applied Bio Materials, Vol. 3, No. 1, 21.01.2020, p. 584-592.

Research output: Contribution to journalArticleResearchpeer-review

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