Effects of solvent in the casting of poly(1-trimethylsilyl-1-propyne) membranes

J. Bi; G. P. Simon; A. Yamasaki; C. L. Wang; Y. Kobayashi; H. J. Griesser

doi:10.1016/S0969-806X(00)00218-8

Effects of solvent in the casting of poly(1-trimethylsilyl-1-propyne) membranes

J. Bi
, G. P. Simon
, A. Yamasaki
, C. L. Wang
, Y. Kobayashi
, H. J. Griesser

Materials Science & Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference Paper › Other

26 Citations (Scopus)

Abstract

Poly(1-trimethylsilyl-1-propyne) (PTMSP) membranes were fabricated by solvent casting from solutions of toluene, cyclohexane and tetrahydrofuran. The effects of the casting solvent on the physical structure of PTMSP were investigated using wide angle X-ray diffraction and positron annihilation lifetime spectroscopy. The permeability of oxygen, nitrogen and carbon dioxide through the cast membranes was also measured. It was found that the nature of the casting solvent markedly influenced the conformation and the free volume of PTMSP, which in turn affected the gas permeability of the cast membranes. Copyright (C) 2000 Elsevier Science Ltd.

Original language	English
Title of host publication	6th International Workshop on Positron and Positronium Chemistry (PPC-6)
Publisher	Elsevier
Pages	563-566
Number of pages	4
Volume	58
Edition	5-6
DOIs	https://doi.org/10.1016/S0969-806X(00)00218-8
Publication status	Published - 1 Jun 2000
Event	International Workshop on Positron and Positronium Chemistry (PPC) 1999 - Tsukuba, Jpn Duration: 7 Jun 1999 → 11 Jun 1999 Conference number: 6th https://www.sciencedirect.com/journal/radiation-physics-and-chemistry/vol/58/issue/5 (Proceedings)

Publication series

Name	Radiation Physics and Chemistry
Publisher	Pergamon
ISSN (Print)	0969-806X

Conference

Conference	International Workshop on Positron and Positronium Chemistry (PPC) 1999
Abbreviated title	PPC-6
City	Tsukuba, Jpn
Period	7/06/99 → 11/06/99
Internet address	https://www.sciencedirect.com/journal/radiation-physics-and-chemistry/vol/58/issue/5 (Proceedings)

Keywords

PALS
Permeability
PTMSP
Solvent effect

Access to Document

10.1016/S0969-806X(00)00218-8

Cite this

Bi, J., Simon, G. P., Yamasaki, A., Wang, C. L., Kobayashi, Y., & Griesser, H. J. (2000). Effects of solvent in the casting of poly(1-trimethylsilyl-1-propyne) membranes. In 6th International Workshop on Positron and Positronium Chemistry (PPC-6) (5-6 ed., Vol. 58, pp. 563-566). (Radiation Physics and Chemistry). Elsevier. https://doi.org/10.1016/S0969-806X(00)00218-8

@inproceedings{daf4588cdf5046988df5f861e19fc4d4,

title = "Effects of solvent in the casting of poly(1-trimethylsilyl-1-propyne) membranes",

abstract = "Poly(1-trimethylsilyl-1-propyne) (PTMSP) membranes were fabricated by solvent casting from solutions of toluene, cyclohexane and tetrahydrofuran. The effects of the casting solvent on the physical structure of PTMSP were investigated using wide angle X-ray diffraction and positron annihilation lifetime spectroscopy. The permeability of oxygen, nitrogen and carbon dioxide through the cast membranes was also measured. It was found that the nature of the casting solvent markedly influenced the conformation and the free volume of PTMSP, which in turn affected the gas permeability of the cast membranes. Copyright (C) 2000 Elsevier Science Ltd.",

keywords = "PALS, Permeability, PTMSP, Solvent effect",

author = "J. Bi and Simon, \{G. P.\} and A. Yamasaki and Wang, \{C. L.\} and Y. Kobayashi and Griesser, \{H. J.\}",

year = "2000",

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doi = "10.1016/S0969-806X(00)00218-8",

language = "English",

volume = "58",

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booktitle = "6th International Workshop on Positron and Positronium Chemistry (PPC-6)",

address = "Netherlands",

edition = "5-6",

note = "International Workshop on Positron and Positronium Chemistry (PPC) 1999, PPC-6 ; Conference date: 07-06-1999 Through 11-06-1999",

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}

Bi, J, Simon, GP, Yamasaki, A, Wang, CL, Kobayashi, Y & Griesser, HJ 2000, Effects of solvent in the casting of poly(1-trimethylsilyl-1-propyne) membranes. in 6th International Workshop on Positron and Positronium Chemistry (PPC-6). 5-6 edn, vol. 58, Radiation Physics and Chemistry, Elsevier, pp. 563-566, International Workshop on Positron and Positronium Chemistry (PPC) 1999, Tsukuba, Jpn, 7/06/99. https://doi.org/10.1016/S0969-806X(00)00218-8

TY - GEN

T1 - Effects of solvent in the casting of poly(1-trimethylsilyl-1-propyne) membranes

AU - Bi, J.

AU - Simon, G. P.

AU - Yamasaki, A.

AU - Wang, C. L.

AU - Kobayashi, Y.

AU - Griesser, H. J.

N1 - Conference code: 6th

PY - 2000/6/1

Y1 - 2000/6/1

N2 - Poly(1-trimethylsilyl-1-propyne) (PTMSP) membranes were fabricated by solvent casting from solutions of toluene, cyclohexane and tetrahydrofuran. The effects of the casting solvent on the physical structure of PTMSP were investigated using wide angle X-ray diffraction and positron annihilation lifetime spectroscopy. The permeability of oxygen, nitrogen and carbon dioxide through the cast membranes was also measured. It was found that the nature of the casting solvent markedly influenced the conformation and the free volume of PTMSP, which in turn affected the gas permeability of the cast membranes. Copyright (C) 2000 Elsevier Science Ltd.

AB - Poly(1-trimethylsilyl-1-propyne) (PTMSP) membranes were fabricated by solvent casting from solutions of toluene, cyclohexane and tetrahydrofuran. The effects of the casting solvent on the physical structure of PTMSP were investigated using wide angle X-ray diffraction and positron annihilation lifetime spectroscopy. The permeability of oxygen, nitrogen and carbon dioxide through the cast membranes was also measured. It was found that the nature of the casting solvent markedly influenced the conformation and the free volume of PTMSP, which in turn affected the gas permeability of the cast membranes. Copyright (C) 2000 Elsevier Science Ltd.

KW - PALS

KW - Permeability

KW - PTMSP

KW - Solvent effect

UR - https://www.scopus.com/pages/publications/0034212608

U2 - 10.1016/S0969-806X(00)00218-8

DO - 10.1016/S0969-806X(00)00218-8

M3 - Conference Paper

AN - SCOPUS:0034212608

VL - 58

T3 - Radiation Physics and Chemistry

SP - 563

EP - 566

BT - 6th International Workshop on Positron and Positronium Chemistry (PPC-6)

PB - Elsevier

T2 - International Workshop on Positron and Positronium Chemistry (PPC) 1999

Y2 - 7 June 1999 through 11 June 1999

ER -

Effects of solvent in the casting of poly(1-trimethylsilyl-1-propyne) membranes

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Keywords

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