Effect of hydrostatic pressure on local polymer dynamics in poly(propylene oxide)

Liliane Bokobza; Philippe Sergot; Lucien Monnerie; F. C.De Schryver; Benny D. Freeman

doi:10.1021/ma00211a026

Effect of hydrostatic pressure on local polymer dynamics in poly(propylene oxide)

Liliane Bokobza
, Philippe Sergot
, Lucien Monnerie
, F. C.De Schryver
, Benny D. Freeman

Research output: Contribution to journal › Article › Research › peer-review

23 Citations (Scopus)

Abstract

The effect of hydrostatic pressure on the local molecular motion in bulk polymers has been studied by measuring the pressure dependence of the fluorescence lifetime of the intramolecular excimerforming probe molecule meso-2,4-di-N-carbazolylpentane dissolved in poly(propylene oxide) of molecular weights 425, 2000, and 4000. The experiments were performed at 313 K and covered a pressure range of 1–3000 bar. The experimental data are compared with the predictions of several free volume based models of polymer dynamics and with previous dipole relaxation measurements of poly(propylene oxide) dynamics.

Original language	English
Pages (from-to)	2566-2573
Number of pages	8
Journal	Macromolecules
Volume	23
Issue number	9
DOIs	https://doi.org/10.1021/ma00211a026
Publication status	Published - 1990
Externally published	Yes

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abstract = "The effect of hydrostatic pressure on the local molecular motion in bulk polymers has been studied by measuring the pressure dependence of the fluorescence lifetime of the intramolecular excimerforming probe molecule meso-2,4-di-N-carbazolylpentane dissolved in poly(propylene oxide) of molecular weights 425, 2000, and 4000. The experiments were performed at 313 K and covered a pressure range of 1–3000 bar. The experimental data are compared with the predictions of several free volume based models of polymer dynamics and with previous dipole relaxation measurements of poly(propylene oxide) dynamics.",

author = "Liliane Bokobza and Philippe Sergot and Lucien Monnerie and Schryver, \{F. C.De\} and Freeman, \{Benny D.\}",

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T1 - Effect of hydrostatic pressure on local polymer dynamics in poly(propylene oxide)

AU - Bokobza, Liliane

AU - Sergot, Philippe

AU - Monnerie, Lucien

AU - Schryver, F. C.De

AU - Freeman, Benny D.

PY - 1990

Y1 - 1990

N2 - The effect of hydrostatic pressure on the local molecular motion in bulk polymers has been studied by measuring the pressure dependence of the fluorescence lifetime of the intramolecular excimerforming probe molecule meso-2,4-di-N-carbazolylpentane dissolved in poly(propylene oxide) of molecular weights 425, 2000, and 4000. The experiments were performed at 313 K and covered a pressure range of 1–3000 bar. The experimental data are compared with the predictions of several free volume based models of polymer dynamics and with previous dipole relaxation measurements of poly(propylene oxide) dynamics.

AB - The effect of hydrostatic pressure on the local molecular motion in bulk polymers has been studied by measuring the pressure dependence of the fluorescence lifetime of the intramolecular excimerforming probe molecule meso-2,4-di-N-carbazolylpentane dissolved in poly(propylene oxide) of molecular weights 425, 2000, and 4000. The experiments were performed at 313 K and covered a pressure range of 1–3000 bar. The experimental data are compared with the predictions of several free volume based models of polymer dynamics and with previous dipole relaxation measurements of poly(propylene oxide) dynamics.

UR - https://www.scopus.com/pages/publications/0025416628

U2 - 10.1021/ma00211a026

DO - 10.1021/ma00211a026

M3 - Article

AN - SCOPUS:0025416628

SN - 0024-9297

VL - 23

SP - 2566

EP - 2573

JO - Macromolecules

JF - Macromolecules

IS - 9

ER -

Effect of hydrostatic pressure on local polymer dynamics in poly(propylene oxide)

Abstract

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