Does functionalisation enhance CO2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

Ravichandar Babarao; Campbell J. Coghlan; Damien Rankine; Witold M. Bloch; Gemma K. Gransbury; Hiroshi Sato; Susumu Kitagawa; Christopher J. Sumby; Matthew R. Hill; Christian J. Doonan

doi:10.1039/c4cc00700j

Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

Ravichandar Babarao, Campbell J. Coghlan, Damien Rankine, Witold M. Bloch, Gemma K. Gransbury, Hiroshi Sato, Susumu Kitagawa, Christopher J. Sumby, Matthew R. Hill, Christian J. Doonan

Research output: Contribution to journal › Article › Research › peer-review

59 Citations (Scopus)

Abstract

The effect of pore functionalisation (-I, -OH, -OCH3) on a series of topologically equivalent, interpenetrated metal-organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO2 was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO2 adsorption.

Original language	English
Pages (from-to)	3238-3241
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	24
DOIs	https://doi.org/10.1039/c4cc00700j
Publication status	Published - 25 Mar 2014
Externally published	Yes

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Cite this

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title = "Does functionalisation enhance CO2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series",

abstract = "The effect of pore functionalisation (-I, -OH, -OCH3) on a series of topologically equivalent, interpenetrated metal-organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO2 was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO2 adsorption.",

author = "Ravichandar Babarao and Coghlan, {Campbell J.} and Damien Rankine and Bloch, {Witold M.} and Gransbury, {Gemma K.} and Hiroshi Sato and Susumu Kitagawa and Sumby, {Christopher J.} and Hill, {Matthew R.} and Doonan, {Christian J.}",

year = "2014",

month = mar,

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doi = "10.1039/c4cc00700j",

language = "English",

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AU - Babarao, Ravichandar

AU - Coghlan, Campbell J.

AU - Rankine, Damien

AU - Bloch, Witold M.

AU - Gransbury, Gemma K.

AU - Sato, Hiroshi

AU - Kitagawa, Susumu

AU - Sumby, Christopher J.

AU - Hill, Matthew R.

AU - Doonan, Christian J.

PY - 2014/3/25

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N2 - The effect of pore functionalisation (-I, -OH, -OCH3) on a series of topologically equivalent, interpenetrated metal-organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO2 was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO2 adsorption.

AB - The effect of pore functionalisation (-I, -OH, -OCH3) on a series of topologically equivalent, interpenetrated metal-organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO2 was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO2 adsorption.

U2 - 10.1039/c4cc00700j

DO - 10.1039/c4cc00700j

M3 - Article

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VL - 50

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JO - Chemical Communications

JF - Chemical Communications

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