Disorder-Induced Material-Insensitive Optical Response in Plasmonic Nanostructures: Vibrant Structural Colors from Noble Metals

Peng Mao, Changxu Liu, Yubiao Niu, Yuyuan Qin, Fengqi Song, Min Han, Richard E. Palmer, Stefan A. Maier, Shuang Zhang

Research output: Contribution to journalArticleResearchpeer-review

26 Citations (Scopus)

Abstract

Materials show various responses to incident light, owing to their unique dielectric functions. A well-known example is the distinct colors displayed by metals, providing probably the simplest method to identify gold, silver, and bronze since ancient times. With the advancement of nanotechnology, optical structures with feature sizes smaller than the optical wavelength have been routinely achieved. In this regime, the optical response is also determined by the geometry of the nanostructures, inspiring flourishing progress in plasmonics, photonic crystals, and metamaterials. Nevertheless, the nature of the materials still plays a decisive role in light–matter interactions, and this material-dependent optical response is widely accepted as a norm in nanophotonics. Here, a counterintuitive system—plasmonic nanostructures composed of different materials but exhibiting almost identical reflection—is proposed and realized. The geometric disorder embedded in the system overwhelms the contribution of the material properties to the electrodynamics. Both numerical simulations and experimental results provide concrete evidence of the insensitivity of the optical response to different plasmonic materials. The same optical response is preserved with various materials, providing great flexibility of freedom in material selection. As a result, the proposed configuration may shed light on novel applications ranging from Raman spectroscopy, photocatalysis, to nonlinear optics.

Original languageEnglish
Article number2007623
Number of pages8
JournalAdvanced Materials
Volume33
Issue number23
DOIs
Publication statusPublished - 10 Jun 2021
Externally publishedYes

Keywords

  • disorder
  • nanophotonics
  • plasmonics

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