Disassembly and reassembly of polyoxometalates: The formation of chains from an adaptable precursor

Chris Ritchie; Colette Boskovic

doi:10.1021/cg901400k

Disassembly and reassembly of polyoxometalates: The formation of chains from an adaptable precursor

Chris Ritchie, Colette Boskovic

Research output: Contribution to journal › Article › Research › peer-review

50 Citations (Scopus)

Abstract

Two one-dimensional chain complexes with building blocks comprised of polyoxotungstate-ligated lanthanoid centers have been synthesized from the adaptable precursor [As₂W₁₉O₆₇(H ₂O)]^14- through combined disassembly and reassembly processes. Careful control of the reaction and crystallization conditions affords compounds formulated as H₃K₇Na₆[Nd ₃As₄W₄₁O₁₄₁OH(H₂O) ₁₀]-60H₂O (1) and KNa[Dy₄As₂W ₂₂O₇₆(H₂O)₁₉(C₂H ₅NO₂)₂]·20.5H₂O (2).

Original language	English
Pages (from-to)	488-491
Number of pages	4
Journal	Crystal Growth & Design
Volume	10
Issue number	2
DOIs	https://doi.org/10.1021/cg901400k
Publication status	Published - 3 Feb 2010
Externally published	Yes

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10.1021/cg901400k

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title = "Disassembly and reassembly of polyoxometalates: The formation of chains from an adaptable precursor",

abstract = "Two one-dimensional chain complexes with building blocks comprised of polyoxotungstate-ligated lanthanoid centers have been synthesized from the adaptable precursor [As2W19O67(H 2O)]14- through combined disassembly and reassembly processes. Careful control of the reaction and crystallization conditions affords compounds formulated as H3K7Na6[Nd 3As4W41O141OH(H2O) 10]-60H2O (1) and KNa[Dy4As2W 22O76(H2O)19(C2H 5NO2)2]·20.5H2O (2).",

author = "Chris Ritchie and Colette Boskovic",

year = "2010",

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day = "3",

doi = "10.1021/cg901400k",

language = "English",

volume = "10",

pages = "488--491",

journal = "Crystal Growth & Design",

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publisher = "American Chemical Society",

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T1 - Disassembly and reassembly of polyoxometalates

T2 - The formation of chains from an adaptable precursor

AU - Ritchie, Chris

AU - Boskovic, Colette

PY - 2010/2/3

Y1 - 2010/2/3

N2 - Two one-dimensional chain complexes with building blocks comprised of polyoxotungstate-ligated lanthanoid centers have been synthesized from the adaptable precursor [As2W19O67(H 2O)]14- through combined disassembly and reassembly processes. Careful control of the reaction and crystallization conditions affords compounds formulated as H3K7Na6[Nd 3As4W41O141OH(H2O) 10]-60H2O (1) and KNa[Dy4As2W 22O76(H2O)19(C2H 5NO2)2]·20.5H2O (2).

AB - Two one-dimensional chain complexes with building blocks comprised of polyoxotungstate-ligated lanthanoid centers have been synthesized from the adaptable precursor [As2W19O67(H 2O)]14- through combined disassembly and reassembly processes. Careful control of the reaction and crystallization conditions affords compounds formulated as H3K7Na6[Nd 3As4W41O141OH(H2O) 10]-60H2O (1) and KNa[Dy4As2W 22O76(H2O)19(C2H 5NO2)2]·20.5H2O (2).

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U2 - 10.1021/cg901400k

DO - 10.1021/cg901400k

M3 - Article

AN - SCOPUS:76349111618

SN - 1528-7483

VL - 10

SP - 488

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JO - Crystal Growth & Design

JF - Crystal Growth & Design

IS - 2

ER -

Disassembly and reassembly of polyoxometalates: The formation of chains from an adaptable precursor

Abstract

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