Directly growing hierarchical nickel-copper hydroxide nanowires on carbon fibre cloth for efficient electrooxidation of ammonia

Wei Xu, Rong Lan, Dongwei Du, John Humphreys, Marc Walker, Zucheng Wu, Huanting Wang, Shanwen Tao

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Ammonia is an attractive carbon-free chemical for electrochemical energy conversion and storage. However, the sluggish kinetic rates of the ammonia electrooxidation reaction, and high cost and poisoning of Pt-based catalysts still remain challenges. This also limits the development of direct ammonia fuel cells. In this work, we directly grew hierarchical mixed NiCu layered hydroxides (LHs) nanowires on carbon fibre cloth electrodes by a facile one-step hydrothermal synthesis method for efficient electro-oxidation of ammonia. This catalyst achieves a current density of 35 mA cm−2 at 0.55 V vs. Ag/AgCl, which is much higher than that of bare Ni(OH)2 catalyst (5 mA cm−2). This is due to abundant active sites and a synergistic effect between Ni and Cu, possibly due to the formation of Ni1−xCuxOOH on the surface of the catalysts through the electrochemical activation of the mixture of Cu(OH)2 and α-Ni(OH)2. In the investigated first row transition elements, it is found that Cu is the sole first-row transition metal to effectively improve activity of Ni(OH)2 for ammonia electrooxidation. This mixed NiCu LHs nano-wire catalyst outperforms commercial Pt/C catalyst in the aspects of ammonia oxidation current and stability, demonstrating it to be a promising low-cost and stable catalyst for efficient ammonia electrooxidation in alkaline condition, which is a potential electrode for ammonia fuel cells for power generation or electrolysis of ammonia for ammonia-containing wastewater treatment.

Original languageEnglish
Pages (from-to)470-479
Number of pages10
JournalApplied Catalysis B: Environmental
Volume218
DOIs
Publication statusPublished - 5 Dec 2017

Keywords

  • Ammonia oxidation
  • Electrocatalyst
  • Hierarchical
  • Layered hydroxide
  • Nano-wire

Cite this

Xu, Wei ; Lan, Rong ; Du, Dongwei ; Humphreys, John ; Walker, Marc ; Wu, Zucheng ; Wang, Huanting ; Tao, Shanwen. / Directly growing hierarchical nickel-copper hydroxide nanowires on carbon fibre cloth for efficient electrooxidation of ammonia. In: Applied Catalysis B: Environmental. 2017 ; Vol. 218. pp. 470-479.
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abstract = "Ammonia is an attractive carbon-free chemical for electrochemical energy conversion and storage. However, the sluggish kinetic rates of the ammonia electrooxidation reaction, and high cost and poisoning of Pt-based catalysts still remain challenges. This also limits the development of direct ammonia fuel cells. In this work, we directly grew hierarchical mixed NiCu layered hydroxides (LHs) nanowires on carbon fibre cloth electrodes by a facile one-step hydrothermal synthesis method for efficient electro-oxidation of ammonia. This catalyst achieves a current density of 35 mA cm−2 at 0.55 V vs. Ag/AgCl, which is much higher than that of bare Ni(OH)2 catalyst (5 mA cm−2). This is due to abundant active sites and a synergistic effect between Ni and Cu, possibly due to the formation of Ni1−xCuxOOH on the surface of the catalysts through the electrochemical activation of the mixture of Cu(OH)2 and α-Ni(OH)2. In the investigated first row transition elements, it is found that Cu is the sole first-row transition metal to effectively improve activity of Ni(OH)2 for ammonia electrooxidation. This mixed NiCu LHs nano-wire catalyst outperforms commercial Pt/C catalyst in the aspects of ammonia oxidation current and stability, demonstrating it to be a promising low-cost and stable catalyst for efficient ammonia electrooxidation in alkaline condition, which is a potential electrode for ammonia fuel cells for power generation or electrolysis of ammonia for ammonia-containing wastewater treatment.",
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Directly growing hierarchical nickel-copper hydroxide nanowires on carbon fibre cloth for efficient electrooxidation of ammonia. / Xu, Wei; Lan, Rong; Du, Dongwei; Humphreys, John; Walker, Marc; Wu, Zucheng; Wang, Huanting; Tao, Shanwen.

In: Applied Catalysis B: Environmental, Vol. 218, 05.12.2017, p. 470-479.

Research output: Contribution to journalArticleResearchpeer-review

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AU - Xu, Wei

AU - Lan, Rong

AU - Du, Dongwei

AU - Humphreys, John

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AU - Wu, Zucheng

AU - Wang, Huanting

AU - Tao, Shanwen

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