Direct formation of propargyltin compounds via C-H activation

Ajdin Kavara; Jeff W. Kampf; Mark M. Banaszak Holl

doi:10.1021/om800132h

Direct formation of propargyltin compounds via C-H activation

Ajdin Kavara, Jeff W. Kampf, Mark M. Banaszak Holl

Research output: Contribution to journal › Article › Other › peer-review

16 Citations (Scopus)

Abstract

The mixed reagent SnC(SiMe₃)₂CH₂CH ₂C(siMe)₂]/ ArI reacts with alkynes to give primary and secondary propargylic C-H activation. Alkynes tested include 1-phenylpropyne, 1-phenylbutyne, 1-trimethylsily1exyne, and 2-hexyne. Aryl halides tested include iodobenzene and 2,4,6-triisopropyliodobenzene. An X-ray crystal structure is reported for the product of the secondary propargylic activation of 2-hexyne.

Original language	English
Pages (from-to)	2896-2897
Number of pages	2
Journal	Organometallics
Volume	27
Issue number	13
DOIs	https://doi.org/10.1021/om800132h
Publication status	Published - 14 Jul 2008
Externally published	Yes

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title = "Direct formation of propargyltin compounds via C-H activation",

abstract = "The mixed reagent SnC(SiMe3)2CH2CH 2C(siMe)2]/ ArI reacts with alkynes to give primary and secondary propargylic C-H activation. Alkynes tested include 1-phenylpropyne, 1-phenylbutyne, 1-trimethylsily1exyne, and 2-hexyne. Aryl halides tested include iodobenzene and 2,4,6-triisopropyliodobenzene. An X-ray crystal structure is reported for the product of the secondary propargylic activation of 2-hexyne.",

author = "Ajdin Kavara and Kampf, {Jeff W.} and {Banaszak Holl}, {Mark M.}",

year = "2008",

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doi = "10.1021/om800132h",

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AU - Kavara, Ajdin

AU - Kampf, Jeff W.

AU - Banaszak Holl, Mark M.

PY - 2008/7/14

Y1 - 2008/7/14

N2 - The mixed reagent SnC(SiMe3)2CH2CH 2C(siMe)2]/ ArI reacts with alkynes to give primary and secondary propargylic C-H activation. Alkynes tested include 1-phenylpropyne, 1-phenylbutyne, 1-trimethylsily1exyne, and 2-hexyne. Aryl halides tested include iodobenzene and 2,4,6-triisopropyliodobenzene. An X-ray crystal structure is reported for the product of the secondary propargylic activation of 2-hexyne.

AB - The mixed reagent SnC(SiMe3)2CH2CH 2C(siMe)2]/ ArI reacts with alkynes to give primary and secondary propargylic C-H activation. Alkynes tested include 1-phenylpropyne, 1-phenylbutyne, 1-trimethylsily1exyne, and 2-hexyne. Aryl halides tested include iodobenzene and 2,4,6-triisopropyliodobenzene. An X-ray crystal structure is reported for the product of the secondary propargylic activation of 2-hexyne.

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VL - 27

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JO - Organometallics

JF - Organometallics

IS - 13

ER -

Direct formation of propargyltin compounds via C-H activation

Abstract

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