Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: Electron deficiency compensation by asymmetric structural changes

Madelyn Qin Yi Tay; Balasubramanian Murugesapandian; Yunpeng Lu; Rakesh Ganguly; Kinjo Rei; Dragoslav Vidović

doi:10.1039/c4dt01210k

Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: Electron deficiency compensation by asymmetric structural changes

Madelyn Qin Yi Tay, Balasubramanian Murugesapandian, Yunpeng Lu, Rakesh Ganguly, Kinjo Rei, Dragoslav Vidović

Research output: Contribution to journal › Article › Research › peer-review

11 Citations (Scopus)

Abstract

The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN₂P ring strain. This journal is

Original language	English
Pages (from-to)	15313-15316
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	41
DOIs	https://doi.org/10.1039/c4dt01210k
Publication status	Published - 7 Nov 2014
Externally published	Yes

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10.1039/c4dt01210k

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abstract = "The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain. This journal is",

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Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: Electron deficiency compensation by asymmetric structural changes. / Tay, Madelyn Qin Yi; Murugesapandian, Balasubramanian; Lu, Yunpeng et al.
In: Dalton Transactions, Vol. 43, No. 41, 07.11.2014, p. 15313-15316.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene

T2 - Electron deficiency compensation by asymmetric structural changes

AU - Tay, Madelyn Qin Yi

AU - Murugesapandian, Balasubramanian

AU - Lu, Yunpeng

AU - Ganguly, Rakesh

AU - Rei, Kinjo

AU - Vidović, Dragoslav

PY - 2014/11/7

Y1 - 2014/11/7

N2 - The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain. This journal is

AB - The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain. This journal is

UR - https://www.scopus.com/pages/publications/84907637755

U2 - 10.1039/c4dt01210k

DO - 10.1039/c4dt01210k

M3 - Article

AN - SCOPUS:84907637755

SN - 1477-9226

VL - 43

SP - 15313

EP - 15316

JO - Dalton Transactions

JF - Dalton Transactions

IS - 41

ER -

Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: Electron deficiency compensation by asymmetric structural changes

Abstract

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