Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: Electron deficiency compensation by asymmetric structural changes

Madelyn Qin Yi Tay, Balasubramanian Murugesapandian, Yunpeng Lu, Rakesh Ganguly, Kinjo Rei, Dragoslav Vidović

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Abstract

The synthesis, characterization and X-ray analysis of dichloro- and dibromo-borenium cations stabilized by a 4-membered carbene are reported. The ligand's structural changes, atypical for similar systems, were caused by coordination to electron deficient fragments and its CN2P ring strain. This journal is

Original languageEnglish
Pages (from-to)15313-15316
Number of pages4
JournalDalton Transactions
Volume43
Issue number41
DOIs
Publication statusPublished - 7 Nov 2014
Externally publishedYes

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