Diffusion enhancements in mineral nanoparticle filled superglassy polymers

Scott T. Matteucci; Victor Kusuma; Benny D. Freeman

Diffusion enhancements in mineral nanoparticle filled superglassy polymers

Scott T. Matteucci, Victor Kusuma, Benny D. Freeman

Research output: Chapter in Book/Report/Conference proceeding › Conference Paper › Other

Abstract

Addition of nanoparticles to high free volume, stiff chain, glassy polymers can increase light gas (CO₂, hydrogen, nitrogen, and methane) permeability with increasing particle loading. Polymer-particle interactions influence the maximum practical particle loading. In this case, light gas diffusivity increases over an order of magnitude relative to that in the unfilled polymer. Polymer-penetrant interactions have a strong influence on gas transport. There are also possibilities for reactions between the particle and penetrants as well. A discussion covers the influence of mineral nanoparticle dispersion on permeability, diffusivity, and solubility in high free volume, stiff chained, glassy polymers; particle dispersion; polymer-particle and penetrant-particle reactions; and the complexity and versatility of mineral filled nanocomposite materials. This is an abstract of a paper presented at the 2006 AIChE Annual Meeting (San Francisco, CA 11/12-17/2006).

Original language	English
Title of host publication	2006 AIChE Annual Meeting
Publisher	American Institute of Chemical Engineers (AIChE)
ISBN (Print)	081691012X, 9780816910120
Publication status	Published - 2006
Externally published	Yes
Event	2006 AIChE Annual Meeting - San Francisco, United States of America Duration: 12 Nov 2006 → 17 Nov 2006

Conference

Conference	2006 AIChE Annual Meeting
Country/Territory	United States of America
City	San Francisco
Period	12/11/06 → 17/11/06

Cite this

@inproceedings{6205ade7188f4828bcc6e3d6d0bc11e2,

title = "Diffusion enhancements in mineral nanoparticle filled superglassy polymers",

abstract = "Addition of nanoparticles to high free volume, stiff chain, glassy polymers can increase light gas (CO2, hydrogen, nitrogen, and methane) permeability with increasing particle loading. Polymer-particle interactions influence the maximum practical particle loading. In this case, light gas diffusivity increases over an order of magnitude relative to that in the unfilled polymer. Polymer-penetrant interactions have a strong influence on gas transport. There are also possibilities for reactions between the particle and penetrants as well. A discussion covers the influence of mineral nanoparticle dispersion on permeability, diffusivity, and solubility in high free volume, stiff chained, glassy polymers; particle dispersion; polymer-particle and penetrant-particle reactions; and the complexity and versatility of mineral filled nanocomposite materials. This is an abstract of a paper presented at the 2006 AIChE Annual Meeting (San Francisco, CA 11/12-17/2006).",

author = "Matteucci, {Scott T.} and Victor Kusuma and Freeman, {Benny D.}",

year = "2006",

language = "English",

isbn = "081691012X",

booktitle = "2006 AIChE Annual Meeting",

publisher = "American Institute of Chemical Engineers (AIChE)",

address = "United States of America",

note = "2006 AIChE Annual Meeting ; Conference date: 12-11-2006 Through 17-11-2006",

}

TY - GEN

T1 - Diffusion enhancements in mineral nanoparticle filled superglassy polymers

AU - Matteucci, Scott T.

AU - Kusuma, Victor

AU - Freeman, Benny D.

PY - 2006

Y1 - 2006

N2 - Addition of nanoparticles to high free volume, stiff chain, glassy polymers can increase light gas (CO2, hydrogen, nitrogen, and methane) permeability with increasing particle loading. Polymer-particle interactions influence the maximum practical particle loading. In this case, light gas diffusivity increases over an order of magnitude relative to that in the unfilled polymer. Polymer-penetrant interactions have a strong influence on gas transport. There are also possibilities for reactions between the particle and penetrants as well. A discussion covers the influence of mineral nanoparticle dispersion on permeability, diffusivity, and solubility in high free volume, stiff chained, glassy polymers; particle dispersion; polymer-particle and penetrant-particle reactions; and the complexity and versatility of mineral filled nanocomposite materials. This is an abstract of a paper presented at the 2006 AIChE Annual Meeting (San Francisco, CA 11/12-17/2006).

AB - Addition of nanoparticles to high free volume, stiff chain, glassy polymers can increase light gas (CO2, hydrogen, nitrogen, and methane) permeability with increasing particle loading. Polymer-particle interactions influence the maximum practical particle loading. In this case, light gas diffusivity increases over an order of magnitude relative to that in the unfilled polymer. Polymer-penetrant interactions have a strong influence on gas transport. There are also possibilities for reactions between the particle and penetrants as well. A discussion covers the influence of mineral nanoparticle dispersion on permeability, diffusivity, and solubility in high free volume, stiff chained, glassy polymers; particle dispersion; polymer-particle and penetrant-particle reactions; and the complexity and versatility of mineral filled nanocomposite materials. This is an abstract of a paper presented at the 2006 AIChE Annual Meeting (San Francisco, CA 11/12-17/2006).

UR - http://www.scopus.com/inward/record.url?scp=58049092815&partnerID=8YFLogxK

M3 - Conference Paper

AN - SCOPUS:58049092815

SN - 081691012X

SN - 9780816910120

BT - 2006 AIChE Annual Meeting

PB - American Institute of Chemical Engineers (AIChE)

T2 - 2006 AIChE Annual Meeting

Y2 - 12 November 2006 through 17 November 2006

ER -

Diffusion enhancements in mineral nanoparticle filled superglassy polymers

Abstract

Conference

Other files and links

Cite this