Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

Todd Scicluna; Benjamin Fraser; Nicole Gorham; Jonathan MacLellan; Massimiliano Massi; Brian Skelton; Timothy St Pierre; Robert Woodward

doi:10.1039/c0ce00036a

Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

Todd Scicluna, Benjamin Fraser, Nicole Gorham, Jonathan MacLellan, Massimiliano Massi, Brian Skelton, Timothy St Pierre, Robert Woodward

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

9 Citations (Scopus)

Abstract

CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl-2], the disubstituted [Co(H2L)(2)][PF6](2), and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [ Co(H2L)(2) (H2L)(4)][PF6](2), as illustrated by X-ray crystal structure analysis.

Original language	English
Pages (from-to)	3422 - 3424
Number of pages	3
Journal	CrystEngComm
Volume	12
Issue number	11
DOIs	https://doi.org/10.1039/c0ce00036a
Publication status	Published - 2010

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10.1039/c0ce00036a

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Cite this

@article{642ee137d551478e8bd2cf58dd2fab46,

title = "Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly",

abstract = "CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl-2], the disubstituted [Co(H2L)(2)][PF6](2), and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [ Co(H2L)(2) (H2L)(4)][PF6](2), as illustrated by X-ray crystal structure analysis.",

author = "Todd Scicluna and Benjamin Fraser and Nicole Gorham and Jonathan MacLellan and Massimiliano Massi and Brian Skelton and {St Pierre}, Timothy and Robert Woodward",

year = "2010",

doi = "10.1039/c0ce00036a",

language = "English",

volume = "12",

pages = "3422 -- 3424",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "The Royal Society of Chemistry",

number = "11",

}

Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly. / Scicluna, Todd; Fraser, Benjamin; Gorham, Nicole; MacLellan, Jonathan; Massi, Massimiliano; Skelton, Brian; St Pierre, Timothy; Woodward, Robert.

In: CrystEngComm, Vol. 12, No. 11, 2010, p. 3422 - 3424.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

AU - Scicluna, Todd

AU - Fraser, Benjamin

AU - Gorham, Nicole

AU - MacLellan, Jonathan

AU - Massi, Massimiliano

AU - Skelton, Brian

AU - St Pierre, Timothy

AU - Woodward, Robert

PY - 2010

Y1 - 2010

N2 - CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl-2], the disubstituted [Co(H2L)(2)][PF6](2), and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [ Co(H2L)(2) (H2L)(4)][PF6](2), as illustrated by X-ray crystal structure analysis.

AB - CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl-2], the disubstituted [Co(H2L)(2)][PF6](2), and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [ Co(H2L)(2) (H2L)(4)][PF6](2), as illustrated by X-ray crystal structure analysis.

UR - http://pubs.rsc.org.ezproxy.lib.monash.edu.au/en/content/articlepdf/2010/ce/c0ce00036a

U2 - 10.1039/c0ce00036a

DO - 10.1039/c0ce00036a

M3 - Article

VL - 12

SP - 3422

EP - 3424

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 11

ER -