Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

Todd Scicluna, Benjamin Fraser, Nicole Gorham, Jonathan MacLellan, Massimiliano Massi, Brian Skelton, Timothy St Pierre, Robert Woodward

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9 Citations (Scopus)

Abstract

CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl-2], the disubstituted [Co(H2L)(2)][PF6](2), and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [ Co(H2L)(2) (H2L)(4)][PF6](2), as illustrated by X-ray crystal structure analysis.
Original languageEnglish
Pages (from-to)3422 - 3424
Number of pages3
JournalCrystEngComm
Volume12
Issue number11
DOIs
Publication statusPublished - 2010

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