DEtermination of trace levels of diazinon and propetamphos in water and sewage by solid phase extraction

L. Villarosa; M. J. McCormick; P. D. Carpenter; P. J. Marriott

doi:10.1080/03067319408033091

DEtermination of trace levels of diazinon and propetamphos in water and sewage by solid phase extraction

L. Villarosa, M. J. McCormick, P. D. Carpenter, P. J. Marriott

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

An analytical method is described for the determination of the organophosphorus pesticides diazinon and propetamphos in water and in sewage, at levels ranging from 0.01-1.0 mg/L. The method involves solid phase extraction using C-18 Bond Elut cartridges, elution with ether, and solvent change to hexane. Quantification of the pesticide is by temperature programmed capillary gas chromatography using a nitrogen—phosphorus detector. Recoveries of diazinon are between 98-102% from water and between 70-80% from activated sludge biomass. These results are compared with a more polar organophosphate, propetamphos, for which the recovery from both water and biomass is close to 100%.

Original language	English
Pages (from-to)	93-103
Number of pages	11
Journal	International Journal of Environmental Analytical Chemistry
Volume	54
Issue number	2
DOIs	https://doi.org/10.1080/03067319408033091
Publication status	Published - 1 Jan 1994
Externally published	Yes

Keywords

Diazinon
gas chromatography with nitrogen-phosphorus detection
mass balance
organophosphate pesticide
propetamphos
sewage
solid-phase extraction
water

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This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1080/03067319408033091

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title = "DEtermination of trace levels of diazinon and propetamphos in water and sewage by solid phase extraction",

abstract = "An analytical method is described for the determination of the organophosphorus pesticides diazinon and propetamphos in water and in sewage, at levels ranging from 0.01-1.0 mg/L. The method involves solid phase extraction using C-18 Bond Elut cartridges, elution with ether, and solvent change to hexane. Quantification of the pesticide is by temperature programmed capillary gas chromatography using a nitrogen—phosphorus detector. Recoveries of diazinon are between 98-102\% from water and between 70-80\% from activated sludge biomass. These results are compared with a more polar organophosphate, propetamphos, for which the recovery from both water and biomass is close to 100\%.",

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author = "L. Villarosa and McCormick, \{M. J.\} and Carpenter, \{P. D.\} and Marriott, \{P. J.\}",

year = "1994",

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doi = "10.1080/03067319408033091",

language = "English",

volume = "54",

pages = "93--103",

journal = "International Journal of Environmental Analytical Chemistry",

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TY - JOUR

T1 - DEtermination of trace levels of diazinon and propetamphos in water and sewage by solid phase extraction

AU - Villarosa, L.

AU - McCormick, M. J.

AU - Carpenter, P. D.

AU - Marriott, P. J.

PY - 1994/1/1

Y1 - 1994/1/1

N2 - An analytical method is described for the determination of the organophosphorus pesticides diazinon and propetamphos in water and in sewage, at levels ranging from 0.01-1.0 mg/L. The method involves solid phase extraction using C-18 Bond Elut cartridges, elution with ether, and solvent change to hexane. Quantification of the pesticide is by temperature programmed capillary gas chromatography using a nitrogen—phosphorus detector. Recoveries of diazinon are between 98-102% from water and between 70-80% from activated sludge biomass. These results are compared with a more polar organophosphate, propetamphos, for which the recovery from both water and biomass is close to 100%.

AB - An analytical method is described for the determination of the organophosphorus pesticides diazinon and propetamphos in water and in sewage, at levels ranging from 0.01-1.0 mg/L. The method involves solid phase extraction using C-18 Bond Elut cartridges, elution with ether, and solvent change to hexane. Quantification of the pesticide is by temperature programmed capillary gas chromatography using a nitrogen—phosphorus detector. Recoveries of diazinon are between 98-102% from water and between 70-80% from activated sludge biomass. These results are compared with a more polar organophosphate, propetamphos, for which the recovery from both water and biomass is close to 100%.

KW - Diazinon

KW - gas chromatography with nitrogen-phosphorus detection

KW - mass balance

KW - organophosphate pesticide

KW - propetamphos

KW - sewage

KW - solid-phase extraction

KW - water

UR - https://www.scopus.com/pages/publications/0028052838

U2 - 10.1080/03067319408033091

DO - 10.1080/03067319408033091

M3 - Article

AN - SCOPUS:0028052838

SN - 0306-7319

VL - 54

SP - 93

EP - 103

JO - International Journal of Environmental Analytical Chemistry

JF - International Journal of Environmental Analytical Chemistry

IS - 2

ER -

DEtermination of trace levels of diazinon and propetamphos in water and sewage by solid phase extraction

Abstract

Keywords

UN SDGs

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