Determination of the propagation rate coefficient of acrylonitrile

Thomas Junkers, Sandy P.S. Koo, Christopher Barner-Kowollik

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17 Citations (Scopus)

Abstract

For the first time, the propagation rate coefficient kp of acrylonitrile has been determined in a broad temperature range in propylene carbonate solution via the pulsed laser polymerization-size exclusion chromatography technique employing a high frequency pulsed laser system. k p was determined to fit the Arrhenius relation ln(kp/L mol-1 s-1) = 14.42 - 1855K/T.

Original languageEnglish
Pages (from-to)438-441
Number of pages4
JournalPolymer Chemistry
Volume1
Issue number4
DOIs
Publication statusPublished - 1 Jun 2010
Externally publishedYes

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