Determination of the propagation rate coefficient of acrylonitrile

Thomas Junkers; Sandy P.S. Koo; Christopher Barner-Kowollik

doi:10.1039/c0py00019a

Determination of the propagation rate coefficient of acrylonitrile

Thomas Junkers, Sandy P.S. Koo, Christopher Barner-Kowollik

Research output: Contribution to journal › Article › Research › peer-review

19 Citations (Scopus)

Abstract

For the first time, the propagation rate coefficient k_p of acrylonitrile has been determined in a broad temperature range in propylene carbonate solution via the pulsed laser polymerization-size exclusion chromatography technique employing a high frequency pulsed laser system. k _p was determined to fit the Arrhenius relation ln(k_p/L mol^-1 s^-1) = 14.42 - 1855K/T.

Original language	English
Pages (from-to)	438-441
Number of pages	4
Journal	Polymer Chemistry
Volume	1
Issue number	4
DOIs	https://doi.org/10.1039/c0py00019a
Publication status	Published - 1 Jun 2010
Externally published	Yes

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title = "Determination of the propagation rate coefficient of acrylonitrile",

abstract = "For the first time, the propagation rate coefficient kp of acrylonitrile has been determined in a broad temperature range in propylene carbonate solution via the pulsed laser polymerization-size exclusion chromatography technique employing a high frequency pulsed laser system. k p was determined to fit the Arrhenius relation ln(kp/L mol-1 s-1) = 14.42 - 1855K/T.",

author = "Thomas Junkers and Koo, {Sandy P.S.} and Christopher Barner-Kowollik",

year = "2010",

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doi = "10.1039/c0py00019a",

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AU - Junkers, Thomas

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AU - Barner-Kowollik, Christopher

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Y1 - 2010/6/1

N2 - For the first time, the propagation rate coefficient kp of acrylonitrile has been determined in a broad temperature range in propylene carbonate solution via the pulsed laser polymerization-size exclusion chromatography technique employing a high frequency pulsed laser system. k p was determined to fit the Arrhenius relation ln(kp/L mol-1 s-1) = 14.42 - 1855K/T.

AB - For the first time, the propagation rate coefficient kp of acrylonitrile has been determined in a broad temperature range in propylene carbonate solution via the pulsed laser polymerization-size exclusion chromatography technique employing a high frequency pulsed laser system. k p was determined to fit the Arrhenius relation ln(kp/L mol-1 s-1) = 14.42 - 1855K/T.

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U2 - 10.1039/c0py00019a

DO - 10.1039/c0py00019a

M3 - Article

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VL - 1

SP - 438

EP - 441

JO - Polymer Chemistry

JF - Polymer Chemistry

SN - 1759-9954

IS - 4

ER -

Determination of the propagation rate coefficient of acrylonitrile

Abstract

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