Determination of aromaticities and other structural features of Australian coals using solid state 13C NMR and FTIR spectroscopies

S. Supaluknari, F. P. Larkins, P. Redlich, W. R. Jackson

Research output: Contribution to journalArticleResearchpeer-review

33 Citations (Scopus)

Abstract

Structural characteristics of 29 Australian coals have been investigated by solid state 13C NMR spectroscopy. A high magnetic field (7.05 T) instrument was used with a spinning sidebands suppression (TOSS) technique to obtain high resolution spectra of coals. Carbon aromaticities of the samples obtained from the experiments are in good agreement with the values derived from normal NMR spectra. They are also compared with aromaticity values derived from FTIR spectra using the Brown-Ladner equation. Good correlations are achieved if the Brown-Ladner equation is corrected for the presence of carbonyl-type carbon species in coals.

Original languageEnglish
Pages (from-to)47-61
Number of pages15
JournalFuel Processing Technology
Volume23
Issue number1
DOIs
Publication statusPublished - 1 Jan 1989

Cite this

Supaluknari, S. ; Larkins, F. P. ; Redlich, P. ; Jackson, W. R. / Determination of aromaticities and other structural features of Australian coals using solid state 13C NMR and FTIR spectroscopies. In: Fuel Processing Technology. 1989 ; Vol. 23, No. 1. pp. 47-61.
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Determination of aromaticities and other structural features of Australian coals using solid state 13C NMR and FTIR spectroscopies. / Supaluknari, S.; Larkins, F. P.; Redlich, P.; Jackson, W. R.

In: Fuel Processing Technology, Vol. 23, No. 1, 01.01.1989, p. 47-61.

Research output: Contribution to journalArticleResearchpeer-review

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