Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex

Tobias Schindler, Albert Paparo, Haruka Nishiyama, Thomas P. Spaniol, Hayato Tsurugi, Kazushi Mashima, Jun Okuda

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Deprotonation of a formato ligand by a cis-coordinated propylidyne ligand in a tungsten(vi) complex [(OSSO)W(CEt)(OCHO)] (3) that contains a tetradentate bis(phenolato) ligand (OSSO = {1,4-dithiabutanediyl-2,2′-bis(4,6-di-tert-butyl-phenolato)}) gave the dioxo complex [(OSSO)WO2] (4) along with CO, ethylene and propylene as major products of decomposition.

Original languageEnglish
Pages (from-to)13328-13331
Number of pages4
JournalDalton Transactions
Volume47
Issue number38
DOIs
Publication statusPublished - 14 Oct 2018
Externally publishedYes

Cite this

Schindler, T., Paparo, A., Nishiyama, H., Spaniol, T. P., Tsurugi, H., Mashima, K., & Okuda, J. (2018). Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex. Dalton Transactions, 47(38), 13328-13331. https://doi.org/10.1039/c8dt03056a
Schindler, Tobias ; Paparo, Albert ; Nishiyama, Haruka ; Spaniol, Thomas P. ; Tsurugi, Hayato ; Mashima, Kazushi ; Okuda, Jun. / Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex. In: Dalton Transactions. 2018 ; Vol. 47, No. 38. pp. 13328-13331.
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abstract = "Deprotonation of a formato ligand by a cis-coordinated propylidyne ligand in a tungsten(vi) complex [(OSSO)W(CEt)(OCHO)] (3) that contains a tetradentate bis(phenolato) ligand (OSSO = {1,4-dithiabutanediyl-2,2′-bis(4,6-di-tert-butyl-phenolato)}) gave the dioxo complex [(OSSO)WO2] (4) along with CO, ethylene and propylene as major products of decomposition.",
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Schindler, T, Paparo, A, Nishiyama, H, Spaniol, TP, Tsurugi, H, Mashima, K & Okuda, J 2018, 'Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex', Dalton Transactions, vol. 47, no. 38, pp. 13328-13331. https://doi.org/10.1039/c8dt03056a

Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex. / Schindler, Tobias; Paparo, Albert; Nishiyama, Haruka; Spaniol, Thomas P.; Tsurugi, Hayato; Mashima, Kazushi; Okuda, Jun.

In: Dalton Transactions, Vol. 47, No. 38, 14.10.2018, p. 13328-13331.

Research output: Contribution to journalArticleResearchpeer-review

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T1 - Deprotonation of a formato ligand by a cis-coordinated carbyne ligand within a bis(phenolate) tungsten complex

AU - Schindler, Tobias

AU - Paparo, Albert

AU - Nishiyama, Haruka

AU - Spaniol, Thomas P.

AU - Tsurugi, Hayato

AU - Mashima, Kazushi

AU - Okuda, Jun

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