TY - JOUR
T1 - Dense arrays of uniform submicron pores in silicon and their applications
AU - Brodoceanu, Daniel
AU - Elnathan, Roey
AU - Prieto-Simón, Beatriz
AU - Delalat, Bahman
AU - Guinan, Taryn
AU - Kroner, Elmar
AU - Voelcker, Nicolas H.
AU - Kraus, Tobias
PY - 2015/1/21
Y1 - 2015/1/21
N2 - We report a versatile particle-based route to dense arrays of parallel submicron pores with high aspect ratio in silicon and explore the application of these arrays in sensors, optics, and polymer micropatterning. Polystyrene (PS) spheres are convectively assembled on gold-coated silicon wafers and sputter-etched, resulting in well-defined gold disc arrays with excellent long-range order. The gold discs act as catalysts in metal-assisted chemical etching, yielding uniform pores with straight walls, flat bottoms, and high aspect ratio. The resulting pore arrays can be used as robust antireflective surfaces, in biosensing applications, and as templates for polymer replica molding.
AB - We report a versatile particle-based route to dense arrays of parallel submicron pores with high aspect ratio in silicon and explore the application of these arrays in sensors, optics, and polymer micropatterning. Polystyrene (PS) spheres are convectively assembled on gold-coated silicon wafers and sputter-etched, resulting in well-defined gold disc arrays with excellent long-range order. The gold discs act as catalysts in metal-assisted chemical etching, yielding uniform pores with straight walls, flat bottoms, and high aspect ratio. The resulting pore arrays can be used as robust antireflective surfaces, in biosensing applications, and as templates for polymer replica molding.
KW - Antireflective surfaces
KW - Colloidal lithography
KW - Metal-assisted chemical etching
KW - Polymer fiber arrays
KW - Porous silicon
KW - SALDI substrates
UR - http://www.scopus.com/inward/record.url?scp=84921526245&partnerID=8YFLogxK
U2 - 10.1021/am506891d
DO - 10.1021/am506891d
M3 - Article
C2 - 25493543
AN - SCOPUS:84921526245
SN - 1944-8244
VL - 7
SP - 1160
EP - 1169
JO - ACS Applied Materials & Interfaces
JF - ACS Applied Materials & Interfaces
IS - 2
ER -