Decarboxylation syntheses of transition metal organometallics. III polyfluorophenylplatinum(II) complexes with nitrogen donor ligands

Glen B. Deacon; Ian L. Grayson

doi:10.1007/BF00618192

Decarboxylation syntheses of transition metal organometallics. III polyfluorophenylplatinum(II) complexes with nitrogen donor ligands

Glen B. Deacon, Ian L. Grayson

School of Chemistry

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29 Citations (Scopus)

Abstract

The platinum(II) carboxylates, trans-Pt(O₂CR)₂(py)₂ and Pt(O₂CR)₂bpy (R=C₆F₅, p-HC₆F₄, m-HC₆F₄, or o-HC₆F₄; bpy=2,2′-bipyridyl), have been prepared by reactions of trans-Pt(OH)₂(py)₂ or Pt(OH)₂bpy with the appropriate polyfluorobenzoic acids, whilst [Pt(py)₄](O₂CC₆F₅)₂ has been obtained from reaction of trans-PtCl₂(py)₂ with thallous pentafluorobenzoate in pyridine at room temperature. In boiling pyridine, the platinum(II) polyfluorobenzoates undergo either decarboxylation giving trans-PtR₂(py)₂ and PtR₂bpy (R= C₆F₅, p-HC₆F₄, or m-HC₆F₄) complexes or substitution, giving [Pt(py)₄](O₂CC₆F₄H-o)₂ and [Ptbpy(py)₂](O₂CC₆F₄H-o)₂. Reactions of trans-PtX₂(py)₂ and PtX₂bpy (X=Cl or Br) with appropriate thallous polyfluorobenzoates in boiling pyridine have yielded the complexes trans-PtR₂(py)₂, PtR₂bpy, PtCl(R)bpy (R=C₆F₅, p-HC₆F₄, or m-HC₆F₄ in each case), trans-PtCl(R)(py)₂ (R = C₆F₅ or m-HC₆F₄), trans-PtBr(C₆F₅)(py)₂, and PtBr(C₆F₅)bpy. The complexes trans-PtR₂(py)₂ (R=C₆F₅ or p-HC₆F₄) have also been prepared from potassium tetrachloroplatinate(II) and the appropriate thallous polyfluorobenzoate in boiling py, and trans-Pt(C₆F₅)₂(py)₂ has been similarly obtained from cis-PtCl₂(py)₂ and C₆F₅CO₂Tl. Significant decarboxylation was not observed on reaction of trans-PtCl₂(py)₂ or PtCl₂bpy with thallous 2,3,4,5-tetrafluorobenzoate.

Original language	English
Pages (from-to)	97-104
Number of pages	8
Journal	Transition Metal Chemistry
Volume	7
Issue number	2
DOIs	https://doi.org/10.1007/BF00618192
Publication status	Published - Apr 1982

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@article{cc8bef333902448f91254c9cb85e3f0c,

title = "Decarboxylation syntheses of transition metal organometallics. III polyfluorophenylplatinum(II) complexes with nitrogen donor ligands",

abstract = "The platinum(II) carboxylates, trans-Pt(O2CR)2(py)2 and Pt(O2CR)2bpy (R=C6F5, p-HC6F4, m-HC6F4, or o-HC6F4; bpy=2,2′-bipyridyl), have been prepared by reactions of trans-Pt(OH)2(py)2 or Pt(OH)2bpy with the appropriate polyfluorobenzoic acids, whilst [Pt(py)4](O2CC6F5)2 has been obtained from reaction of trans-PtCl2(py)2 with thallous pentafluorobenzoate in pyridine at room temperature. In boiling pyridine, the platinum(II) polyfluorobenzoates undergo either decarboxylation giving trans-PtR2(py)2 and PtR2bpy (R= C6F5, p-HC6F4, or m-HC6F4) complexes or substitution, giving [Pt(py)4](O2CC6F4H-o)2 and [Ptbpy(py)2](O2CC6F4H-o)2. Reactions of trans-PtX2(py)2 and PtX2bpy (X=Cl or Br) with appropriate thallous polyfluorobenzoates in boiling pyridine have yielded the complexes trans-PtR2(py)2, PtR2bpy, PtCl(R)bpy (R=C6F5, p-HC6F4, or m-HC6F4 in each case), trans-PtCl(R)(py)2 (R = C6F5 or m-HC6F4), trans-PtBr(C6F5)(py)2, and PtBr(C6F5)bpy. The complexes trans-PtR2(py)2 (R=C6F5 or p-HC6F4) have also been prepared from potassium tetrachloroplatinate(II) and the appropriate thallous polyfluorobenzoate in boiling py, and trans-Pt(C6F5)2(py)2 has been similarly obtained from cis-PtCl2(py)2 and C6F5CO2Tl. Significant decarboxylation was not observed on reaction of trans-PtCl2(py)2 or PtCl2bpy with thallous 2,3,4,5-tetrafluorobenzoate.",

author = "Deacon, \{Glen B.\} and Grayson, \{Ian L.\}",

year = "1982",

month = apr,

doi = "10.1007/BF00618192",

language = "English",

volume = "7",

pages = "97--104",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer-Verlag London Ltd.",

number = "2",

}

TY - JOUR

T1 - Decarboxylation syntheses of transition metal organometallics. III polyfluorophenylplatinum(II) complexes with nitrogen donor ligands

AU - Deacon, Glen B.

AU - Grayson, Ian L.

PY - 1982/4

Y1 - 1982/4

N2 - The platinum(II) carboxylates, trans-Pt(O2CR)2(py)2 and Pt(O2CR)2bpy (R=C6F5, p-HC6F4, m-HC6F4, or o-HC6F4; bpy=2,2′-bipyridyl), have been prepared by reactions of trans-Pt(OH)2(py)2 or Pt(OH)2bpy with the appropriate polyfluorobenzoic acids, whilst [Pt(py)4](O2CC6F5)2 has been obtained from reaction of trans-PtCl2(py)2 with thallous pentafluorobenzoate in pyridine at room temperature. In boiling pyridine, the platinum(II) polyfluorobenzoates undergo either decarboxylation giving trans-PtR2(py)2 and PtR2bpy (R= C6F5, p-HC6F4, or m-HC6F4) complexes or substitution, giving [Pt(py)4](O2CC6F4H-o)2 and [Ptbpy(py)2](O2CC6F4H-o)2. Reactions of trans-PtX2(py)2 and PtX2bpy (X=Cl or Br) with appropriate thallous polyfluorobenzoates in boiling pyridine have yielded the complexes trans-PtR2(py)2, PtR2bpy, PtCl(R)bpy (R=C6F5, p-HC6F4, or m-HC6F4 in each case), trans-PtCl(R)(py)2 (R = C6F5 or m-HC6F4), trans-PtBr(C6F5)(py)2, and PtBr(C6F5)bpy. The complexes trans-PtR2(py)2 (R=C6F5 or p-HC6F4) have also been prepared from potassium tetrachloroplatinate(II) and the appropriate thallous polyfluorobenzoate in boiling py, and trans-Pt(C6F5)2(py)2 has been similarly obtained from cis-PtCl2(py)2 and C6F5CO2Tl. Significant decarboxylation was not observed on reaction of trans-PtCl2(py)2 or PtCl2bpy with thallous 2,3,4,5-tetrafluorobenzoate.

AB - The platinum(II) carboxylates, trans-Pt(O2CR)2(py)2 and Pt(O2CR)2bpy (R=C6F5, p-HC6F4, m-HC6F4, or o-HC6F4; bpy=2,2′-bipyridyl), have been prepared by reactions of trans-Pt(OH)2(py)2 or Pt(OH)2bpy with the appropriate polyfluorobenzoic acids, whilst [Pt(py)4](O2CC6F5)2 has been obtained from reaction of trans-PtCl2(py)2 with thallous pentafluorobenzoate in pyridine at room temperature. In boiling pyridine, the platinum(II) polyfluorobenzoates undergo either decarboxylation giving trans-PtR2(py)2 and PtR2bpy (R= C6F5, p-HC6F4, or m-HC6F4) complexes or substitution, giving [Pt(py)4](O2CC6F4H-o)2 and [Ptbpy(py)2](O2CC6F4H-o)2. Reactions of trans-PtX2(py)2 and PtX2bpy (X=Cl or Br) with appropriate thallous polyfluorobenzoates in boiling pyridine have yielded the complexes trans-PtR2(py)2, PtR2bpy, PtCl(R)bpy (R=C6F5, p-HC6F4, or m-HC6F4 in each case), trans-PtCl(R)(py)2 (R = C6F5 or m-HC6F4), trans-PtBr(C6F5)(py)2, and PtBr(C6F5)bpy. The complexes trans-PtR2(py)2 (R=C6F5 or p-HC6F4) have also been prepared from potassium tetrachloroplatinate(II) and the appropriate thallous polyfluorobenzoate in boiling py, and trans-Pt(C6F5)2(py)2 has been similarly obtained from cis-PtCl2(py)2 and C6F5CO2Tl. Significant decarboxylation was not observed on reaction of trans-PtCl2(py)2 or PtCl2bpy with thallous 2,3,4,5-tetrafluorobenzoate.

UR - https://www.scopus.com/pages/publications/0008859981

U2 - 10.1007/BF00618192

DO - 10.1007/BF00618192

M3 - Article

AN - SCOPUS:0008859981

SN - 0340-4285

VL - 7

SP - 97

EP - 104

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 2

ER -

Decarboxylation syntheses of transition metal organometallics. III polyfluorophenylplatinum(II) complexes with nitrogen donor ligands

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