Crystal structure of bis(benzo[h]quinolin-10-yl-C10,N)dicarbonylruthenium(II)

Jennifer M Patrick; Allan H. White; Michael I. Bruce; Mark J. Beatson; David St C Black; Glen B. Deacon; Nicholas C. Thomas

doi:10.1039/DT9830002121

Crystal structure of bis(benzo[h]quinolin-10-yl-C¹⁰,N)dicarbonylruthenium(II)

Jennifer M Patrick, Allan H. White, Michael I. Bruce, Mark J. Beatson, David St C Black, Glen B. Deacon, Nicholas C. Thomas

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

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Abstract

The crystal structure of the cis isomer of the title compound, cis-[Ru(CO)₂(bquin)₂] (bquin = benzo[h]quinolin-10-yl), has been established at 295 K by single-crystal X-ray diffraction methods, and refined by least squares to a residual of 0.037 for 1 242 independent 'observed' reflections. Crystals are monoclinic, space group Pn, with a = 13.682(4), b = 10.885(3), c = 7.497(2) Å, β = 104.05(2)°, and Z = 2. The two carbonyl groups [Ru-C 1.87(1) and 1.81(1) Å] lie trans to the two ligand nitrogen atoms [Ru-N 2.15(1) and 2.16(1) Å]; Ru-C(ligand) are 2.13(1) and 2.12(1) Å.

Original language	English
Pages (from-to)	2121-2123
Number of pages	3
Journal	Dalton Transactions
Issue number	9
DOIs	https://doi.org/10.1039/DT9830002121
Publication status	Published - 1983

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@article{7bd06e6ada3f485380e6f92cd4c36bc4,

title = "Crystal structure of bis(benzo[h]quinolin-10-yl-C10,N)dicarbonylruthenium(II)",

abstract = "The crystal structure of the cis isomer of the title compound, cis-[Ru(CO)2(bquin)2] (bquin = benzo[h]quinolin-10-yl), has been established at 295 K by single-crystal X-ray diffraction methods, and refined by least squares to a residual of 0.037 for 1 242 independent 'observed' reflections. Crystals are monoclinic, space group Pn, with a = 13.682(4), b = 10.885(3), c = 7.497(2) {\AA}, β = 104.05(2)°, and Z = 2. The two carbonyl groups [Ru-C 1.87(1) and 1.81(1) {\AA}] lie trans to the two ligand nitrogen atoms [Ru-N 2.15(1) and 2.16(1) {\AA}]; Ru-C(ligand) are 2.13(1) and 2.12(1) {\AA}.",

author = "Patrick, {Jennifer M} and White, {Allan H.} and Bruce, {Michael I.} and Beatson, {Mark J.} and Black, {David St C} and Deacon, {Glen B.} and Thomas, {Nicholas C.}",

year = "1983",

doi = "10.1039/DT9830002121",

language = "English",

pages = "2121--2123",

journal = "Dalton Transactions",

issn = "1472-7773",

publisher = "The Royal Society of Chemistry",

number = "9",

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TY - JOUR

T1 - Crystal structure of bis(benzo[h]quinolin-10-yl-C10,N)dicarbonylruthenium(II)

AU - Patrick, Jennifer M

AU - White, Allan H.

AU - Bruce, Michael I.

AU - Beatson, Mark J.

AU - Black, David St C

AU - Deacon, Glen B.

AU - Thomas, Nicholas C.

PY - 1983

Y1 - 1983

N2 - The crystal structure of the cis isomer of the title compound, cis-[Ru(CO)2(bquin)2] (bquin = benzo[h]quinolin-10-yl), has been established at 295 K by single-crystal X-ray diffraction methods, and refined by least squares to a residual of 0.037 for 1 242 independent 'observed' reflections. Crystals are monoclinic, space group Pn, with a = 13.682(4), b = 10.885(3), c = 7.497(2) Å, β = 104.05(2)°, and Z = 2. The two carbonyl groups [Ru-C 1.87(1) and 1.81(1) Å] lie trans to the two ligand nitrogen atoms [Ru-N 2.15(1) and 2.16(1) Å]; Ru-C(ligand) are 2.13(1) and 2.12(1) Å.

AB - The crystal structure of the cis isomer of the title compound, cis-[Ru(CO)2(bquin)2] (bquin = benzo[h]quinolin-10-yl), has been established at 295 K by single-crystal X-ray diffraction methods, and refined by least squares to a residual of 0.037 for 1 242 independent 'observed' reflections. Crystals are monoclinic, space group Pn, with a = 13.682(4), b = 10.885(3), c = 7.497(2) Å, β = 104.05(2)°, and Z = 2. The two carbonyl groups [Ru-C 1.87(1) and 1.81(1) Å] lie trans to the two ligand nitrogen atoms [Ru-N 2.15(1) and 2.16(1) Å]; Ru-C(ligand) are 2.13(1) and 2.12(1) Å.

UR - http://www.scopus.com/inward/record.url?scp=37049111892&partnerID=8YFLogxK

U2 - 10.1039/DT9830002121

DO - 10.1039/DT9830002121

M3 - Article

SN - 1472-7773

SP - 2121

EP - 2123

JO - Dalton Transactions

JF - Dalton Transactions

IS - 9

ER -

Crystal structure of bis(benzo[h]quinolin-10-yl-C10,N)dicarbonylruthenium(II)

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Crystal structure of bis(benzo[h]quinolin-10-yl-C¹⁰,N)dicarbonylruthenium(II)