Crystal engineering of dichromate pillared hybrid ultramicroporous materials incorporating pyrazole-based ligands

Hayley Scott, Soumya Mukherjee, David R Turner, Matthew Polson, Michael Zaworotko, Paul Kruger

Research output: Contribution to journalArticleResearchpeer-review

4 Citations (Scopus)

Abstract

Two new coordination networks of formula [Cu(L)2(Cr2O7)], DICRO-L-Cu, (L = 7: 4-(3,5-dimethyl-1H-pyrazol-4-yl)pyridine; 8: 3,3′,5,5′-tetramethyl-1H,1′H-4,4′-bipyrazole) are reported. These compounds represent the first examples of hybrid ultramicroporous materials incorporating pyrazole-based ligands. Ligand length and sterics mitigate against interpenetration between networks, generating internal voids which have been studied in terms of CO2 and N2 sorption.

Original languageEnglish
Pages (from-to)1193-1197
Number of pages5
JournalCrystEngComm
Volume20
Issue number9
DOIs
Publication statusPublished - 1 Jan 2018

Keywords

  • Metal-organic framework (MOF)
  • Crystallography

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