CO2 capture from air using supported polyethyleneimine type sorbent

Romesh P. Wijesiri; Gregory P. Knowles; Hasina Yeasmin; Andrew F.A. Hoadley; Alan L. Chaffee

doi:10.2139/ssrn.3366330

CO₂ capture from air using supported polyethyleneimine type sorbent

Romesh P. Wijesiri, Gregory P. Knowles, Hasina Yeasmin, Andrew F.A. Hoadley, Alan L. Chaffee

Research output: Chapter in Book/Report/Conference proceeding › Conference Paper › Other

1 Citation (Scopus)

Abstract

The potential of a highly loaded mesocellular silica supported polyethyleneimine sorbent to capture CO2 from air was investigated under a set of isothermal conditions between 36 °C and 81 °C. The highest capacity, 1.29 mmol/g, was observed at temperatures of 46 °C and 52 °C. At temperatures lower than 46 °C, the uptake of CO2 appeared to be limited by gas diffusion resistances, while at temperatures above 52 °C the uptake appeared to be limited by the thermodynamics of the reaction between CO2 and amines.

Original language	English
Title of host publication	SSRN
Subtitle of host publication	GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies
Publisher	SSRN
Number of pages	5
DOIs	https://doi.org/10.2139/ssrn.3366330
Publication status	Published - 2018
Event	International Conference on Greenhouse Gas Control Technologies 2018 - Melbourne, Australia Duration: 21 Oct 2018 → 25 Oct 2018 Conference number: 14th https://ghgt.info (Website)

Conference

Conference	International Conference on Greenhouse Gas Control Technologies 2018
Abbreviated title	GHGT 2018
Country/Territory	Australia
City	Melbourne
Period	21/10/18 → 25/10/18
Internet address	https://ghgt.info (Website)

Keywords

adsorption
CO2
direct air capture
polyethyleneimine
solid supported amine

Access to Document

10.2139/ssrn.3366330Licence: Unspecified

Cite this

@inproceedings{c71b5b19c6944b70a3ea977c52c7f986,

title = "CO2 capture from air using supported polyethyleneimine type sorbent",

abstract = "The potential of a highly loaded mesocellular silica supported polyethyleneimine sorbent to capture CO2 from air was investigated under a set of isothermal conditions between 36 °C and 81 °C. The highest capacity, 1.29 mmol/g, was observed at temperatures of 46 °C and 52 °C. At temperatures lower than 46 °C, the uptake of CO2 appeared to be limited by gas diffusion resistances, while at temperatures above 52 °C the uptake appeared to be limited by the thermodynamics of the reaction between CO2 and amines.",

keywords = "adsorption, CO2, direct air capture, polyethyleneimine, solid supported amine",

author = "Wijesiri, {Romesh P.} and Knowles, {Gregory P.} and Hasina Yeasmin and Hoadley, {Andrew F.A.} and Chaffee, {Alan L.}",

note = "Funding Information: The authors acknowledge Antonio Benci and David Zuidemma, Monash Instrumentation Facility for assistance in designing and programming some of the componentry in the experimental set up. The authors also acknowledge Zhijian Liang for the production of the MCF and MCF-PEI powder precursors. Publisher Copyright: {\textcopyright} 2018 GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies. All rights reserved.; International Conference on Greenhouse Gas Control Technologies 2018, GHGT 2018 ; Conference date: 21-10-2018 Through 25-10-2018",

year = "2018",

doi = "10.2139/ssrn.3366330",

language = "English",

booktitle = "SSRN",

publisher = "SSRN",

address = "United States of America",

url = "https://ghgt.info",

}

Wijesiri, RP, Knowles, GP, Yeasmin, H, Hoadley, AFA & Chaffee, AL 2018, CO₂ capture from air using supported polyethyleneimine type sorbent. in SSRN: GHGT 2018 - 14th International Conference on Greenhouse Gas Control Technologies. SSRN, International Conference on Greenhouse Gas Control Technologies 2018, Melbourne, Victoria, Australia, 21/10/18. https://doi.org/10.2139/ssrn.3366330

TY - GEN

T1 - CO2 capture from air using supported polyethyleneimine type sorbent

AU - Wijesiri, Romesh P.

AU - Knowles, Gregory P.

AU - Yeasmin, Hasina

AU - Hoadley, Andrew F.A.

AU - Chaffee, Alan L.

N1 - Conference code: 14th

PY - 2018

Y1 - 2018

N2 - The potential of a highly loaded mesocellular silica supported polyethyleneimine sorbent to capture CO2 from air was investigated under a set of isothermal conditions between 36 °C and 81 °C. The highest capacity, 1.29 mmol/g, was observed at temperatures of 46 °C and 52 °C. At temperatures lower than 46 °C, the uptake of CO2 appeared to be limited by gas diffusion resistances, while at temperatures above 52 °C the uptake appeared to be limited by the thermodynamics of the reaction between CO2 and amines.

AB - The potential of a highly loaded mesocellular silica supported polyethyleneimine sorbent to capture CO2 from air was investigated under a set of isothermal conditions between 36 °C and 81 °C. The highest capacity, 1.29 mmol/g, was observed at temperatures of 46 °C and 52 °C. At temperatures lower than 46 °C, the uptake of CO2 appeared to be limited by gas diffusion resistances, while at temperatures above 52 °C the uptake appeared to be limited by the thermodynamics of the reaction between CO2 and amines.

KW - adsorption

KW - CO2

KW - direct air capture

KW - polyethyleneimine

KW - solid supported amine

UR - http://www.scopus.com/inward/record.url?scp=85111478969&partnerID=8YFLogxK

U2 - 10.2139/ssrn.3366330

DO - 10.2139/ssrn.3366330

M3 - Conference Paper

AN - SCOPUS:85111478969

BT - SSRN

PB - SSRN

T2 - International Conference on Greenhouse Gas Control Technologies 2018

Y2 - 21 October 2018 through 25 October 2018

ER -