Copper-catalyzed oxidative decarboxylative couplings of sulfoximines and aryl propiolic acids

Daniel Priebbenow; Peter Becker; Carsten Bolm

doi:10.1021/ol403106e

Copper-catalyzed oxidative decarboxylative couplings of sulfoximines and aryl propiolic acids

Daniel Priebbenow, Peter Becker, Carsten Bolm

Research output: Contribution to journal › Article › Research › peer-review

89 Citations (Scopus)

Abstract

A method has been developed for the preparation of N-alkynylated sulfoximines involving the copper-catalyzed decarboxylative coupling of sulfoximines with aryl propiolic acids. A range of substituents on both the sulfoximidoyl moiety and the aryl group of the propiolic acid were compatible with this reaction process to afford a series of sulfoximidoyl-functionalized alkynes.

Original language	English
Pages (from-to)	6155 - 6157
Number of pages	3
Journal	Organic Letters
Volume	15
Issue number	24
DOIs	https://doi.org/10.1021/ol403106e
Publication status	Published - 2013
Externally published	Yes

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10.1021/ol403106e

Cite this

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title = "Copper-catalyzed oxidative decarboxylative couplings of sulfoximines and aryl propiolic acids",

abstract = "A method has been developed for the preparation of N-alkynylated sulfoximines involving the copper-catalyzed decarboxylative coupling of sulfoximines with aryl propiolic acids. A range of substituents on both the sulfoximidoyl moiety and the aryl group of the propiolic acid were compatible with this reaction process to afford a series of sulfoximidoyl-functionalized alkynes.",

author = "Daniel Priebbenow and Peter Becker and Carsten Bolm",

year = "2013",

doi = "10.1021/ol403106e",

language = "English",

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pages = "6155 -- 6157",

journal = "Organic Letters",

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number = "24",

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T1 - Copper-catalyzed oxidative decarboxylative couplings of sulfoximines and aryl propiolic acids

AU - Priebbenow, Daniel

AU - Becker, Peter

AU - Bolm, Carsten

PY - 2013

Y1 - 2013

N2 - A method has been developed for the preparation of N-alkynylated sulfoximines involving the copper-catalyzed decarboxylative coupling of sulfoximines with aryl propiolic acids. A range of substituents on both the sulfoximidoyl moiety and the aryl group of the propiolic acid were compatible with this reaction process to afford a series of sulfoximidoyl-functionalized alkynes.

AB - A method has been developed for the preparation of N-alkynylated sulfoximines involving the copper-catalyzed decarboxylative coupling of sulfoximines with aryl propiolic acids. A range of substituents on both the sulfoximidoyl moiety and the aryl group of the propiolic acid were compatible with this reaction process to afford a series of sulfoximidoyl-functionalized alkynes.

U2 - 10.1021/ol403106e

DO - 10.1021/ol403106e

M3 - Article

VL - 15

SP - 6155

EP - 6157

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 24

ER -