Copolymerization of a novel substituted methacrylamide with methyl methacrylate

Dax Kukulj, Thomas P. Davis, Robert P. Burford, Liam P. Devlin

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Abstract

The copolymerization behaviour of the adduct of N′,N′-dimethylaminopropyl methacrylamide and epichlorohydrin (DMAPMA-Epi) and methyl methacrylate (MMA) was investigated. The reactivity ratios for the MMA (1)/DMAPMA-Epi (2) couple in solution, using various regression methods based on the Mayo-Lewis model, are r1 = 1.73 and r2 = 0.03. The Q and e values for DMAPMA-Epi are estimated to be 0.23 and -1.32 respectively. On the basis of the reactivity ratios, theoretical curves for the instantaneous copolymer composition throughout conversion have been calculated.

Original languageEnglish
Pages (from-to)3579-3582
Number of pages4
JournalPolymer
Volume35
Issue number16
DOIs
Publication statusPublished - 1 Jan 1994
Externally publishedYes

Keywords

  • copolymerization
  • methacrylamide
  • reactivity ratios

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