Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

Michael A. Land, Bright Huo, Katherine N. Robertson, Kai E.O. Ylijoki, Peter T.K. Lee, Jetsuda Areephong, Dragoslav Vidović, Jason A.C. Clyburne

Research output: Contribution to journalArticleResearchpeer-review

Abstract

In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.

Original languageEnglish
Pages (from-to)10195-10205
Number of pages11
JournalDalton Transactions
Volume47
Issue number30
DOIs
Publication statusPublished - 1 Jan 2018

Keywords

  • Ligands
  • X-ray diffraction
  • Atoms

Cite this

Land, M. A., Huo, B., Robertson, K. N., Ylijoki, K. E. O., Lee, P. T. K., Areephong, J., ... Clyburne, J. A. C. (2018). Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes. Dalton Transactions, 47(30), 10195-10205. https://doi.org/10.1039/c8dt01875h
Land, Michael A. ; Huo, Bright ; Robertson, Katherine N. ; Ylijoki, Kai E.O. ; Lee, Peter T.K. ; Areephong, Jetsuda ; Vidović, Dragoslav ; Clyburne, Jason A.C. / Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes. In: Dalton Transactions. 2018 ; Vol. 47, No. 30. pp. 10195-10205.
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Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes. / Land, Michael A.; Huo, Bright; Robertson, Katherine N.; Ylijoki, Kai E.O.; Lee, Peter T.K.; Areephong, Jetsuda; Vidović, Dragoslav; Clyburne, Jason A.C.

In: Dalton Transactions, Vol. 47, No. 30, 01.01.2018, p. 10195-10205.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

AU - Land, Michael A.

AU - Huo, Bright

AU - Robertson, Katherine N.

AU - Ylijoki, Kai E.O.

AU - Lee, Peter T.K.

AU - Areephong, Jetsuda

AU - Vidović, Dragoslav

AU - Clyburne, Jason A.C.

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AB - In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.

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KW - X-ray diffraction

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