Abstract
In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.
| Original language | English |
|---|---|
| Pages (from-to) | 10195-10205 |
| Number of pages | 11 |
| Journal | Dalton Transactions |
| Volume | 47 |
| Issue number | 30 |
| DOIs | |
| Publication status | Published - 1 Jan 2018 |
Keywords
- Ligands
- X-ray diffraction
- Atoms
Cite this
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Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes. / Land, Michael A.; Huo, Bright; Robertson, Katherine N.; Ylijoki, Kai E.O.; Lee, Peter T.K.; Areephong, Jetsuda; Vidović, Dragoslav; Clyburne, Jason A.C.
In: Dalton Transactions, Vol. 47, No. 30, 01.01.2018, p. 10195-10205.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes
AU - Land, Michael A.
AU - Huo, Bright
AU - Robertson, Katherine N.
AU - Ylijoki, Kai E.O.
AU - Lee, Peter T.K.
AU - Areephong, Jetsuda
AU - Vidović, Dragoslav
AU - Clyburne, Jason A.C.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.
AB - In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.
KW - Ligands
KW - X-ray diffraction
KW - Atoms
UR - http://www.scopus.com/inward/record.url?scp=85050871797&partnerID=8YFLogxK
U2 - 10.1039/c8dt01875h
DO - 10.1039/c8dt01875h
M3 - Article
VL - 47
SP - 10195
EP - 10205
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
SN - 1477-9226
IS - 30
ER -