Abstract
In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.
Original language | English |
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Pages (from-to) | 10195-10205 |
Number of pages | 11 |
Journal | Dalton Transactions |
Volume | 47 |
Issue number | 30 |
DOIs | |
Publication status | Published - 1 Jan 2018 |
Keywords
- Ligands
- X-ray diffraction
- Atoms