Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

Michael A. Land; Bright Huo; Katherine N. Robertson; Kai E.O. Ylijoki; Peter T.K. Lee; Jetsuda Areephong; Dragoslav Vidović; Jason A.C. Clyburne

doi:10.1039/c8dt01875h

Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

Michael A. Land, Bright Huo, Katherine N. Robertson, Kai E.O. Ylijoki, Peter T.K. Lee, Jetsuda Areephong, Dragoslav Vidović, Jason A.C. Clyburne

School of Chemistry

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3 Citations (Scopus)

Abstract

In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.

Original language	English
Pages (from-to)	10195-10205
Number of pages	11
Journal	Dalton Transactions
Volume	47
Issue number	30
DOIs	https://doi.org/10.1039/c8dt01875h
Publication status	Published - 1 Jan 2018

Keywords

Ligands
X-ray diffraction
Atoms

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10.1039/c8dt01875h

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Land, Michael A. ; Huo, Bright ; Robertson, Katherine N. ; Ylijoki, Kai E.O. ; Lee, Peter T.K. ; Areephong, Jetsuda ; Vidović, Dragoslav ; Clyburne, Jason A.C. / Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes. In: Dalton Transactions. 2018 ; Vol. 47, No. 30. pp. 10195-10205.

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keywords = "Ligands, X-ray diffraction, Atoms",

author = "Land, {Michael A.} and Bright Huo and Robertson, {Katherine N.} and Ylijoki, {Kai E.O.} and Lee, {Peter T.K.} and Jetsuda Areephong and Dragoslav Vidovi{\'c} and Clyburne, {Jason A.C.}",

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doi = "10.1039/c8dt01875h",

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Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes. / Land, Michael A.; Huo, Bright; Robertson, Katherine N.; Ylijoki, Kai E.O.; Lee, Peter T.K.; Areephong, Jetsuda; Vidović, Dragoslav; Clyburne, Jason A.C.

In: Dalton Transactions, Vol. 47, No. 30, 01.01.2018, p. 10195-10205.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

AU - Land, Michael A.

AU - Huo, Bright

AU - Robertson, Katherine N.

AU - Ylijoki, Kai E.O.

AU - Lee, Peter T.K.

AU - Areephong, Jetsuda

AU - Vidović, Dragoslav

AU - Clyburne, Jason A.C.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.

AB - In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N′-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac.

KW - Ligands

KW - X-ray diffraction

KW - Atoms

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U2 - 10.1039/c8dt01875h

DO - 10.1039/c8dt01875h

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AN - SCOPUS:85050871797

VL - 47

SP - 10195

EP - 10205

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 30

ER -

Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes

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Keywords

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