Coordination induced atropisomerism in an NHC-based rhodium macrocycle

Rhiann E Andrew, Dominic W Ferdani, Christian Andre Ohlin, Adrian B Chaplin

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Reversible interaction with carbon monoxide results in the onset of dynamic atropisomerism at 298 K in an otherwise static NHC-based rhodium pincer complex, [Rh(C^N^C-(CH2)12)(CO)][BArF4] (1, ArF = 3,5-C6H3(CF3)2). The mechanism of this process has been comprehensively interrogated by a combination of variable-temperature NMR spectroscopy, IR spectroscopy, and computational modeling. In addition, a structural analogue of a high-energy symmetrical intermediate species—invoked in the process but not directly observed spectroscopically—has been prepared and characterized in solution and the solid-state.
Original languageEnglish
Pages (from-to)913-917
Number of pages5
Issue number5
Publication statusPublished - 2015

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