Converting 3D rigid metal-organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation

Yingdian He; Jin Shang; Qinfen Gu; Gang Li; Jiaye Li; Ranjeet Kaur Singh; Penny Yuezhu Xiao; Paul Anthony Webley

doi:10.1039/c5cc05867h

Converting 3D rigid metal-organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation

Yingdian He, Jin Shang, Qinfen Gu, Gang Li, Jiaye Li, Ranjeet Kaur Singh, Penny Yuezhu Xiao, Paul Anthony Webley

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

54 Citations (Scopus)

Abstract

We report a synthetic strategy for constructing a novel flexible MOF from a rigid parent structure by ligand exchange. This is the first reported study on introducing flexible heterogeneity into a rigid structure via substantial structural rearrangement. The daughter material exhibits enhanced gas separation selectivity compared with the parent.

Original language	English
Pages (from-to)	14716-14719
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	79
DOIs	https://doi.org/10.1039/c5cc05867h
Publication status	Published - 2015

Access to Document

10.1039/c5cc05867h

Cite this

@article{b928a38b36d24a789c72873a776b71fc,

title = "Converting 3D rigid metal-organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation",

abstract = "We report a synthetic strategy for constructing a novel flexible MOF from a rigid parent structure by ligand exchange. This is the first reported study on introducing flexible heterogeneity into a rigid structure via substantial structural rearrangement. The daughter material exhibits enhanced gas separation selectivity compared with the parent.",

author = "Yingdian He and Jin Shang and Qinfen Gu and Gang Li and Jiaye Li and Singh, \{Ranjeet Kaur\} and Xiao, \{Penny Yuezhu\} and Webley, \{Paul Anthony\}",

year = "2015",

doi = "10.1039/c5cc05867h",

language = "English",

volume = "51",

pages = "14716--14719",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "79",

}

TY - JOUR

T1 - Converting 3D rigid metal-organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation

AU - He, Yingdian

AU - Shang, Jin

AU - Gu, Qinfen

AU - Li, Gang

AU - Li, Jiaye

AU - Singh, Ranjeet Kaur

AU - Xiao, Penny Yuezhu

AU - Webley, Paul Anthony

PY - 2015

Y1 - 2015

N2 - We report a synthetic strategy for constructing a novel flexible MOF from a rigid parent structure by ligand exchange. This is the first reported study on introducing flexible heterogeneity into a rigid structure via substantial structural rearrangement. The daughter material exhibits enhanced gas separation selectivity compared with the parent.

AB - We report a synthetic strategy for constructing a novel flexible MOF from a rigid parent structure by ligand exchange. This is the first reported study on introducing flexible heterogeneity into a rigid structure via substantial structural rearrangement. The daughter material exhibits enhanced gas separation selectivity compared with the parent.

UR - http://pubs.rsc.org.ezproxy.lib.monash.edu.au/en/content/articlepdf/2015/cc/c5cc05867h

UR - https://www.scopus.com/pages/publications/84942155072

U2 - 10.1039/c5cc05867h

DO - 10.1039/c5cc05867h

M3 - Article

SN - 1359-7345

VL - 51

SP - 14716

EP - 14719

JO - Chemical Communications

JF - Chemical Communications

IS - 79

ER -

Converting 3D rigid metal-organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation

Abstract

Access to Document

Other files and links

Cite this