Controlled synthesis of MDMO-PPV and block copolymers made thereof

Joke Vandenbergh; Inge Cosemans; Laurence Lutsen; Dirk Vanderzande; Thomas Junkers

doi:10.1039/c2py00551d

Controlled synthesis of MDMO-PPV and block copolymers made thereof

Joke Vandenbergh, Inge Cosemans, Laurence Lutsen, Dirk Vanderzande, Thomas Junkers

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

Poly[2-methoxy-5-(3,7-dimethyloctyloxy)-1,4-phenylene-vinylene] (MDMO-PPV) with various average molecular weights was directly synthesized via the sulfinyl precursor route by employing excess amounts of CBr ₄ as control agent. Bromine functional materials were obtained in the range of a few thousand to close to 80000 g mol ^-1. Also, block copolymers have become available via reactivation of the chains in ATRP.

Original language	English
Pages (from-to)	1722-1725
Number of pages	4
Journal	Polymer Chemistry
Volume	3
Issue number	7
DOIs	https://doi.org/10.1039/c2py00551d
Publication status	Published - 1 Jul 2012
Externally published	Yes

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abstract = "Poly[2-methoxy-5-(3,7-dimethyloctyloxy)-1,4-phenylene-vinylene] (MDMO-PPV) with various average molecular weights was directly synthesized via the sulfinyl precursor route by employing excess amounts of CBr 4 as control agent. Bromine functional materials were obtained in the range of a few thousand to close to 80000 g mol -1. Also, block copolymers have become available via reactivation of the chains in ATRP.",

author = "Joke Vandenbergh and Inge Cosemans and Laurence Lutsen and Dirk Vanderzande and Thomas Junkers",

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AU - Vandenbergh, Joke

AU - Cosemans, Inge

AU - Lutsen, Laurence

AU - Vanderzande, Dirk

AU - Junkers, Thomas

PY - 2012/7/1

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N2 - Poly[2-methoxy-5-(3,7-dimethyloctyloxy)-1,4-phenylene-vinylene] (MDMO-PPV) with various average molecular weights was directly synthesized via the sulfinyl precursor route by employing excess amounts of CBr 4 as control agent. Bromine functional materials were obtained in the range of a few thousand to close to 80000 g mol -1. Also, block copolymers have become available via reactivation of the chains in ATRP.

AB - Poly[2-methoxy-5-(3,7-dimethyloctyloxy)-1,4-phenylene-vinylene] (MDMO-PPV) with various average molecular weights was directly synthesized via the sulfinyl precursor route by employing excess amounts of CBr 4 as control agent. Bromine functional materials were obtained in the range of a few thousand to close to 80000 g mol -1. Also, block copolymers have become available via reactivation of the chains in ATRP.

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DO - 10.1039/c2py00551d

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Controlled synthesis of MDMO-PPV and block copolymers made thereof

Abstract

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