Controlled polymerization of acrylates and methacrylates

T. P. Davis; D. M. Haddleton; S. N. Richards

doi:10.1080/15321799408009636

Controlled polymerization of acrylates and methacrylates

T. P. Davis, D. M. Haddleton, S. N. Richards

Research output: Contribution to journal › Article › Research › peer-review

174 Citations (Scopus)

Abstract

The paper presents recent advances in the controlled polymerization of methacrylates and acrylates. The concept of control is discussed with regards to molecular weight, stereospecificity, rate/exotherm, chain architecture and introduction of functionality. A number of methods such as classical anionic polymerization, metal free anionic polymerization, group transfer polymerization, immortal polymerization, and screened anionic polymerization and their similarities are also discussed and viewed as spectrum of related mechanisms.

Original language	English
Pages (from-to)	243-324
Number of pages	82
Journal	Journal of Macromolecular Science, Part C: Polymer Reviews
Volume	34
Issue number	2
DOIs	https://doi.org/10.1080/15321799408009636
Publication status	Published - 1 May 1994
Externally published	Yes

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10.1080/15321799408009636

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AB - The paper presents recent advances in the controlled polymerization of methacrylates and acrylates. The concept of control is discussed with regards to molecular weight, stereospecificity, rate/exotherm, chain architecture and introduction of functionality. A number of methods such as classical anionic polymerization, metal free anionic polymerization, group transfer polymerization, immortal polymerization, and screened anionic polymerization and their similarities are also discussed and viewed as spectrum of related mechanisms.

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Controlled polymerization of acrylates and methacrylates

Abstract

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