Control of polymer structure by chain transfer processes

Ezio Rizzardo; Y. K. Chong; Richard A. Evans; Graeme Moad; San H. Thang

Control of polymer structure by chain transfer processes

Ezio Rizzardo, Y. K. Chong, Richard A. Evans, Graeme Moad, San H. Thang

Research output: Contribution to journal › Article › Research › peer-review

Abstract

Chain transfer can be performed effectively by a mechanism of addition-fragmentation with appropriately substituted allylic compounds, vinyl ethers and thionoesters. Selection of substituents allows the optimization of chain transfer activity and the preparation of macromonomers and other end-functional polymers from acrylates, methacrylates, styrene and vinyl acetate. The addition-fragmentation concept has been extended to the free radical ring-opening polymerization of cyclic allylic sulfides.

Original language	English
Pages (from-to)	1-11
Number of pages	11
Journal	Macromolecular Symposia
Volume	111
Publication status	Published - 1 Dec 1996
Externally published	Yes

Cite this

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title = "Control of polymer structure by chain transfer processes",

abstract = "Chain transfer can be performed effectively by a mechanism of addition-fragmentation with appropriately substituted allylic compounds, vinyl ethers and thionoesters. Selection of substituents allows the optimization of chain transfer activity and the preparation of macromonomers and other end-functional polymers from acrylates, methacrylates, styrene and vinyl acetate. The addition-fragmentation concept has been extended to the free radical ring-opening polymerization of cyclic allylic sulfides.",

author = "Ezio Rizzardo and Chong, \{Y. K.\} and Evans, \{Richard A.\} and Graeme Moad and Thang, \{San H.\}",

year = "1996",

month = dec,

day = "1",

language = "English",

volume = "111",

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journal = "Macromolecular Symposia",

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publisher = "Wiley-VCH Verlag GmbH \& Co. KGaA",

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T1 - Control of polymer structure by chain transfer processes

AU - Rizzardo, Ezio

AU - Chong, Y. K.

AU - Evans, Richard A.

AU - Moad, Graeme

AU - Thang, San H.

PY - 1996/12/1

Y1 - 1996/12/1

N2 - Chain transfer can be performed effectively by a mechanism of addition-fragmentation with appropriately substituted allylic compounds, vinyl ethers and thionoesters. Selection of substituents allows the optimization of chain transfer activity and the preparation of macromonomers and other end-functional polymers from acrylates, methacrylates, styrene and vinyl acetate. The addition-fragmentation concept has been extended to the free radical ring-opening polymerization of cyclic allylic sulfides.

AB - Chain transfer can be performed effectively by a mechanism of addition-fragmentation with appropriately substituted allylic compounds, vinyl ethers and thionoesters. Selection of substituents allows the optimization of chain transfer activity and the preparation of macromonomers and other end-functional polymers from acrylates, methacrylates, styrene and vinyl acetate. The addition-fragmentation concept has been extended to the free radical ring-opening polymerization of cyclic allylic sulfides.

UR - https://www.scopus.com/pages/publications/0030356666

M3 - Article

AN - SCOPUS:0030356666

SN - 1022-1360

VL - 111

SP - 1

EP - 11

JO - Macromolecular Symposia

JF - Macromolecular Symposia

ER -

Control of polymer structure by chain transfer processes

Abstract

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