Control of interpenetration in two-dimensional metal-organic frameworks by modification of hydrogen bonding capability of the organic bridging subunits

Masoumeh Servati-Gargari, Ghodrat Mahmoudi, Stuart Robert Batten, Vladimir Stilinovic, Derek Butler, Laurance G Beauvais, William Scott Kassel, William G Dougherty, Donald VanDerveer

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23 Citations (Scopus)

Abstract

Six coordination polymers were prepared by linking Mn(SCN)2 units by three different bis(4-pyridyl) substituited hydrazone derivatives (L) in three different solvents (methanol, ethanol, and acetonitrile) in order to study the effect of the hydrogen bonding ability of L on the formation of solvates rather than interpenetrated solvent-free interpenetrated structures. When the ligand L which cannot act as a hydrogen donor was used, in all three solvents the same product was obtained. This was a [Mn(SCN)2L2]n metal-organic framework, consisting of two-dimensional (2D) networks, each interpenetrating two neighboring ones. When the bridging ligands L have additional functional groups capable of acting as hydrogen donors or acceptors, synthesis from acetonitrile yields non-interpenetrating 2D [Mn(SCN)2L2]n networks with solvent molecules occupying the voids of the network. Other solvents were found to yield interpenetrated solvent free networks, or they replaced some of the L ligands, forming one-dimensional coordination polymers
Original languageEnglish
Pages (from-to)1336-1343
Number of pages8
JournalCrystal Growth and Design
Volume15
Issue number3
DOIs
Publication statusPublished - 2015

Cite this

Servati-Gargari, Masoumeh ; Mahmoudi, Ghodrat ; Batten, Stuart Robert ; Stilinovic, Vladimir ; Butler, Derek ; Beauvais, Laurance G ; Kassel, William Scott ; Dougherty, William G ; VanDerveer, Donald. / Control of interpenetration in two-dimensional metal-organic frameworks by modification of hydrogen bonding capability of the organic bridging subunits. In: Crystal Growth and Design. 2015 ; Vol. 15, No. 3. pp. 1336-1343.
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title = "Control of interpenetration in two-dimensional metal-organic frameworks by modification of hydrogen bonding capability of the organic bridging subunits",
abstract = "Six coordination polymers were prepared by linking Mn(SCN)2 units by three different bis(4-pyridyl) substituited hydrazone derivatives (L) in three different solvents (methanol, ethanol, and acetonitrile) in order to study the effect of the hydrogen bonding ability of L on the formation of solvates rather than interpenetrated solvent-free interpenetrated structures. When the ligand L which cannot act as a hydrogen donor was used, in all three solvents the same product was obtained. This was a [Mn(SCN)2L2]n metal-organic framework, consisting of two-dimensional (2D) networks, each interpenetrating two neighboring ones. When the bridging ligands L have additional functional groups capable of acting as hydrogen donors or acceptors, synthesis from acetonitrile yields non-interpenetrating 2D [Mn(SCN)2L2]n networks with solvent molecules occupying the voids of the network. Other solvents were found to yield interpenetrated solvent free networks, or they replaced some of the L ligands, forming one-dimensional coordination polymers",
author = "Masoumeh Servati-Gargari and Ghodrat Mahmoudi and Batten, {Stuart Robert} and Vladimir Stilinovic and Derek Butler and Beauvais, {Laurance G} and Kassel, {William Scott} and Dougherty, {William G} and Donald VanDerveer",
year = "2015",
doi = "10.1021/cg501741r",
language = "English",
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pages = "1336--1343",
journal = "Crystal Growth and Design",
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Servati-Gargari, M, Mahmoudi, G, Batten, SR, Stilinovic, V, Butler, D, Beauvais, LG, Kassel, WS, Dougherty, WG & VanDerveer, D 2015, 'Control of interpenetration in two-dimensional metal-organic frameworks by modification of hydrogen bonding capability of the organic bridging subunits', Crystal Growth and Design, vol. 15, no. 3, pp. 1336-1343. https://doi.org/10.1021/cg501741r

Control of interpenetration in two-dimensional metal-organic frameworks by modification of hydrogen bonding capability of the organic bridging subunits. / Servati-Gargari, Masoumeh; Mahmoudi, Ghodrat; Batten, Stuart Robert; Stilinovic, Vladimir; Butler, Derek; Beauvais, Laurance G; Kassel, William Scott; Dougherty, William G; VanDerveer, Donald.

In: Crystal Growth and Design, Vol. 15, No. 3, 2015, p. 1336-1343.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Control of interpenetration in two-dimensional metal-organic frameworks by modification of hydrogen bonding capability of the organic bridging subunits

AU - Servati-Gargari, Masoumeh

AU - Mahmoudi, Ghodrat

AU - Batten, Stuart Robert

AU - Stilinovic, Vladimir

AU - Butler, Derek

AU - Beauvais, Laurance G

AU - Kassel, William Scott

AU - Dougherty, William G

AU - VanDerveer, Donald

PY - 2015

Y1 - 2015

N2 - Six coordination polymers were prepared by linking Mn(SCN)2 units by three different bis(4-pyridyl) substituited hydrazone derivatives (L) in three different solvents (methanol, ethanol, and acetonitrile) in order to study the effect of the hydrogen bonding ability of L on the formation of solvates rather than interpenetrated solvent-free interpenetrated structures. When the ligand L which cannot act as a hydrogen donor was used, in all three solvents the same product was obtained. This was a [Mn(SCN)2L2]n metal-organic framework, consisting of two-dimensional (2D) networks, each interpenetrating two neighboring ones. When the bridging ligands L have additional functional groups capable of acting as hydrogen donors or acceptors, synthesis from acetonitrile yields non-interpenetrating 2D [Mn(SCN)2L2]n networks with solvent molecules occupying the voids of the network. Other solvents were found to yield interpenetrated solvent free networks, or they replaced some of the L ligands, forming one-dimensional coordination polymers

AB - Six coordination polymers were prepared by linking Mn(SCN)2 units by three different bis(4-pyridyl) substituited hydrazone derivatives (L) in three different solvents (methanol, ethanol, and acetonitrile) in order to study the effect of the hydrogen bonding ability of L on the formation of solvates rather than interpenetrated solvent-free interpenetrated structures. When the ligand L which cannot act as a hydrogen donor was used, in all three solvents the same product was obtained. This was a [Mn(SCN)2L2]n metal-organic framework, consisting of two-dimensional (2D) networks, each interpenetrating two neighboring ones. When the bridging ligands L have additional functional groups capable of acting as hydrogen donors or acceptors, synthesis from acetonitrile yields non-interpenetrating 2D [Mn(SCN)2L2]n networks with solvent molecules occupying the voids of the network. Other solvents were found to yield interpenetrated solvent free networks, or they replaced some of the L ligands, forming one-dimensional coordination polymers

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