Contrasting reductions of group 14 metal(II) chloride complexes: Synthesis of a beta-diketiminato tin(I) dimer

Sam Lim Choong, Christian Schenk, Andreas Stasch, Deepak Sadashiv Dange, Cameron Jones

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52 Citations (Scopus)

Abstract

Reductions of the beta-diketiminato group 14 metal(II) chloride complexes, [((But)MesNacnac) ECl] ((But)MesNacnac = [(MesNCBu(t))(2)CH](-); Mes = mesityl; E = Ge, Sn or Pb), with a magnesium(I) dimer have led to differing outcomes, which include the formation of the first beta-diketiminato group 14 metal(I) dimer, [ ((But)MesNacnac)Sn (2)].
Original languageEnglish
Pages (from-to)2504 - 2506
Number of pages3
JournalChemical Communications
Volume48
Issue number19
DOIs
Publication statusPublished - 2012

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