Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst

Li Yan; Yunjie Ding; Hejun Zhu; Hongmei Yin; Guiping Jiao; Dongyuan Zhao; Liwu Lin

doi:10.1016/S1872-2067(06)60001-6

Continuous fixed-bed gas-phase hydroformylation over PPh₃-modified mesostructured cellular foam-supported Rh catalyst

Li Yan, Yunjie Ding, Hejun Zhu, Hongmei Yin, Guiping Jiao, Dongyuan Zhao, Liwu Lin

Research output: Contribution to journal › Article › Research › peer-review

6 Citations (Scopus)

Abstract

Mesostructured cellular foams (MCF) were used as supports in developing a PPh₃-Rh/MCF catalyst as a practical application for these materials. The turnover frequency of butyraldehyde, conversion of propylene, and regioselectivity for butyraldehyde over PPh₃-Rh/MCF were comparable to those over the immobilized homogeneous catalyst (HRh(CO)(PPh₃)₃/MCF) when there was 80% exposure of the rhodium metal. The (PPh₃)₃/MCF) catalyst showed a far higher activity and selectivity than the classical heterogeneous Rh/MCF catalyst. The HRh(CO)(PPh₃)₃/MCF catalyst reached its highest activity at about 10 hr, and then decreased rapidly. The stability of the PPh₃-Rh/MCF catalyst was maintained for about 250 hr.

Original language	English
Pages (from-to)	1-3
Number of pages	3
Journal	Chinese Journal of Catalysis
Volume	27
Issue number	1
DOIs	https://doi.org/10.1016/S1872-2067(06)60001-6
Publication status	Published - 1 Jan 2006
Externally published	Yes

Keywords

Hydroformylation
Mesostructured cellular foam
Propylene
Rhodium
Supported catalyst
Triphenyl phosphine

Access to Document

10.1016/S1872-2067(06)60001-6

Cite this

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title = "Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst",

abstract = "Mesostructured cellular foams (MCF) were used as supports in developing a PPh3-Rh/MCF catalyst as a practical application for these materials. The turnover frequency of butyraldehyde, conversion of propylene, and regioselectivity for butyraldehyde over PPh3-Rh/MCF were comparable to those over the immobilized homogeneous catalyst (HRh(CO)(PPh3)3/MCF) when there was 80% exposure of the rhodium metal. The (PPh3)3/MCF) catalyst showed a far higher activity and selectivity than the classical heterogeneous Rh/MCF catalyst. The HRh(CO)(PPh3)3/MCF catalyst reached its highest activity at about 10 hr, and then decreased rapidly. The stability of the PPh3-Rh/MCF catalyst was maintained for about 250 hr.",

keywords = "Hydroformylation, Mesostructured cellular foam, Propylene, Rhodium, Supported catalyst, Triphenyl phosphine",

author = "Li Yan and Yunjie Ding and Hejun Zhu and Hongmei Yin and Guiping Jiao and Dongyuan Zhao and Liwu Lin",

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T1 - Continuous fixed-bed gas-phase hydroformylation over PPh3-modified mesostructured cellular foam-supported Rh catalyst

AU - Yan, Li

AU - Ding, Yunjie

AU - Zhu, Hejun

AU - Yin, Hongmei

AU - Jiao, Guiping

AU - Zhao, Dongyuan

AU - Lin, Liwu

PY - 2006/1/1

Y1 - 2006/1/1

N2 - Mesostructured cellular foams (MCF) were used as supports in developing a PPh3-Rh/MCF catalyst as a practical application for these materials. The turnover frequency of butyraldehyde, conversion of propylene, and regioselectivity for butyraldehyde over PPh3-Rh/MCF were comparable to those over the immobilized homogeneous catalyst (HRh(CO)(PPh3)3/MCF) when there was 80% exposure of the rhodium metal. The (PPh3)3/MCF) catalyst showed a far higher activity and selectivity than the classical heterogeneous Rh/MCF catalyst. The HRh(CO)(PPh3)3/MCF catalyst reached its highest activity at about 10 hr, and then decreased rapidly. The stability of the PPh3-Rh/MCF catalyst was maintained for about 250 hr.

AB - Mesostructured cellular foams (MCF) were used as supports in developing a PPh3-Rh/MCF catalyst as a practical application for these materials. The turnover frequency of butyraldehyde, conversion of propylene, and regioselectivity for butyraldehyde over PPh3-Rh/MCF were comparable to those over the immobilized homogeneous catalyst (HRh(CO)(PPh3)3/MCF) when there was 80% exposure of the rhodium metal. The (PPh3)3/MCF) catalyst showed a far higher activity and selectivity than the classical heterogeneous Rh/MCF catalyst. The HRh(CO)(PPh3)3/MCF catalyst reached its highest activity at about 10 hr, and then decreased rapidly. The stability of the PPh3-Rh/MCF catalyst was maintained for about 250 hr.

KW - Hydroformylation

KW - Mesostructured cellular foam

KW - Propylene

KW - Rhodium

KW - Supported catalyst

KW - Triphenyl phosphine

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