Conjugate addition of the anion derived from 3-(phenylsulfiny1)prop-1-ene to cyclopent-2-en-1-one

Malcolm R. Binns; Richard K. Haynes; Timothy L. Houston; W. Roy Jackson

doi:10.1071/CH9812465

Conjugate addition of the anion derived from 3-(phenylsulfiny1)prop-1-ene to cyclopent-2-en-1-one

Malcolm R. Binns, Richard K. Haynes, Timothy L. Houston, W. Roy Jackson

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

The title anion in tetrahydrofuran containing one equivalent of hexamethylphosphoric triamide at -78° undergoes a rapid conjugate addition reaction with cyclopent-2-en-1-one. The sole product obtained, in 73% yield, is (E)-3-[3-(phenylsulfinyl)prop-2-enyl]cyclopentan-l-one.

Original language	English
Pages (from-to)	2465-2467
Number of pages	3
Journal	Australian Journal of Chemistry
Volume	34
Issue number	11
DOIs	https://doi.org/10.1071/CH9812465
Publication status	Published - 1 Jan 1981
Externally published	Yes

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title = "Conjugate addition of the anion derived from 3-(phenylsulfiny1)prop-1-ene to cyclopent-2-en-1-one",

abstract = "The title anion in tetrahydrofuran containing one equivalent of hexamethylphosphoric triamide at -78° undergoes a rapid conjugate addition reaction with cyclopent-2-en-1-one. The sole product obtained, in 73% yield, is (E)-3-[3-(phenylsulfinyl)prop-2-enyl]cyclopentan-l-one.",

author = "Binns, {Malcolm R.} and Haynes, {Richard K.} and Houston, {Timothy L.} and {Roy Jackson}, W.",

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AU - Roy Jackson, W.

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N2 - The title anion in tetrahydrofuran containing one equivalent of hexamethylphosphoric triamide at -78° undergoes a rapid conjugate addition reaction with cyclopent-2-en-1-one. The sole product obtained, in 73% yield, is (E)-3-[3-(phenylsulfinyl)prop-2-enyl]cyclopentan-l-one.

AB - The title anion in tetrahydrofuran containing one equivalent of hexamethylphosphoric triamide at -78° undergoes a rapid conjugate addition reaction with cyclopent-2-en-1-one. The sole product obtained, in 73% yield, is (E)-3-[3-(phenylsulfinyl)prop-2-enyl]cyclopentan-l-one.

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Conjugate addition of the anion derived from 3-(phenylsulfiny1)prop-1-ene to cyclopent-2-en-1-one

Abstract

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