Confinement-induced giant spin-orbit-coupled magnetic moment of Co nanoclusters in TiO2 films

Xiang Ding, Xiangyuan Cui, Chi Xiao, Xi Luo, Nina Bao, Andrivo Rusydi, Xiaojiang Yu, Zunming Lu, Yonghua Du, Xinwei Guan, Li-Ting Tseng, Wai Tung Lee, Sohail Ahmed, Rongkun Zheng, Tao Liu, Tom Wu, Jun Ding, Kiyonori Suzuki, Valeria Lauter, Ajayan VinuSimon P. Ringer, Jia Bao Yi

Research output: Contribution to journalArticleResearchpeer-review

Abstract

High magnetization materials are in great demand for the fabrication of advanced multifunctional magnetic devices. Notwithstanding this demand, the development of new materials with these attributes has been relatively slow. In this work, we propose a new strategy to achieve high magnetic moments above room temperature. Our material engineering approach invoked the embedding of magnetic nanoclusters in an oxide matrix. By precisely controlling pulsed laser deposition parameters, Co nanoclusters are formed in a 5 at % Co-TiO2 film. The presence of these nanoclusters was confirmed using transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray absorption fine structure. The film exhibits a very high saturation magnetization of 99 emu/cm3. Detailed studies using X-ray magnetic circular dichroism confirm that Co has an enhanced magnetic moment of 3.5 μB/atom, while the Ti and O also contribute to the magnetic moments. First-principles calculations supported our hypothesis that the metallic Co nanoclusters surrounded by a TiO2 matrix can exhibit both large spin and orbital moments. Moreover, a quantum confinement effect results in a high Curie temperature for the embedded Co nanoclusters. These findings reveal that 1-2 nm nanoclusters that are quantum confined can exhibit very large magnetic moments above room temperature, representing a promising advance for the design of new high magnetization materials.

Original languageEnglish
Pages (from-to)43781-43788
Number of pages8
JournalACS Applied Materials and Interfaces
Volume11
Issue number46
DOIs
Publication statusPublished - 20 Nov 2019

Keywords

  • enhanced magnetic moment
  • ferromagnetism
  • nanoclusters
  • quantum confinement effect
  • TiO

Cite this

Ding, Xiang ; Cui, Xiangyuan ; Xiao, Chi ; Luo, Xi ; Bao, Nina ; Rusydi, Andrivo ; Yu, Xiaojiang ; Lu, Zunming ; Du, Yonghua ; Guan, Xinwei ; Tseng, Li-Ting ; Lee, Wai Tung ; Ahmed, Sohail ; Zheng, Rongkun ; Liu, Tao ; Wu, Tom ; Ding, Jun ; Suzuki, Kiyonori ; Lauter, Valeria ; Vinu, Ajayan ; Ringer, Simon P. ; Yi, Jia Bao. / Confinement-induced giant spin-orbit-coupled magnetic moment of Co nanoclusters in TiO2 films. In: ACS Applied Materials and Interfaces. 2019 ; Vol. 11, No. 46. pp. 43781-43788.
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title = "Confinement-induced giant spin-orbit-coupled magnetic moment of Co nanoclusters in TiO2 films",
abstract = "High magnetization materials are in great demand for the fabrication of advanced multifunctional magnetic devices. Notwithstanding this demand, the development of new materials with these attributes has been relatively slow. In this work, we propose a new strategy to achieve high magnetic moments above room temperature. Our material engineering approach invoked the embedding of magnetic nanoclusters in an oxide matrix. By precisely controlling pulsed laser deposition parameters, Co nanoclusters are formed in a 5 at {\%} Co-TiO2 film. The presence of these nanoclusters was confirmed using transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray absorption fine structure. The film exhibits a very high saturation magnetization of 99 emu/cm3. Detailed studies using X-ray magnetic circular dichroism confirm that Co has an enhanced magnetic moment of 3.5 μB/atom, while the Ti and O also contribute to the magnetic moments. First-principles calculations supported our hypothesis that the metallic Co nanoclusters surrounded by a TiO2 matrix can exhibit both large spin and orbital moments. Moreover, a quantum confinement effect results in a high Curie temperature for the embedded Co nanoclusters. These findings reveal that 1-2 nm nanoclusters that are quantum confined can exhibit very large magnetic moments above room temperature, representing a promising advance for the design of new high magnetization materials.",
keywords = "enhanced magnetic moment, ferromagnetism, nanoclusters, quantum confinement effect, TiO",
author = "Xiang Ding and Xiangyuan Cui and Chi Xiao and Xi Luo and Nina Bao and Andrivo Rusydi and Xiaojiang Yu and Zunming Lu and Yonghua Du and Xinwei Guan and Li-Ting Tseng and Lee, {Wai Tung} and Sohail Ahmed and Rongkun Zheng and Tao Liu and Tom Wu and Jun Ding and Kiyonori Suzuki and Valeria Lauter and Ajayan Vinu and Ringer, {Simon P.} and Yi, {Jia Bao}",
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journal = "ACS Applied Materials and Interfaces",
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Ding, X, Cui, X, Xiao, C, Luo, X, Bao, N, Rusydi, A, Yu, X, Lu, Z, Du, Y, Guan, X, Tseng, L-T, Lee, WT, Ahmed, S, Zheng, R, Liu, T, Wu, T, Ding, J, Suzuki, K, Lauter, V, Vinu, A, Ringer, SP & Yi, JB 2019, 'Confinement-induced giant spin-orbit-coupled magnetic moment of Co nanoclusters in TiO2 films', ACS Applied Materials and Interfaces, vol. 11, no. 46, pp. 43781-43788. https://doi.org/10.1021/acsami.9b15823

Confinement-induced giant spin-orbit-coupled magnetic moment of Co nanoclusters in TiO2 films. / Ding, Xiang; Cui, Xiangyuan; Xiao, Chi; Luo, Xi; Bao, Nina; Rusydi, Andrivo; Yu, Xiaojiang; Lu, Zunming; Du, Yonghua; Guan, Xinwei; Tseng, Li-Ting; Lee, Wai Tung; Ahmed, Sohail; Zheng, Rongkun; Liu, Tao; Wu, Tom; Ding, Jun; Suzuki, Kiyonori; Lauter, Valeria; Vinu, Ajayan; Ringer, Simon P.; Yi, Jia Bao.

In: ACS Applied Materials and Interfaces, Vol. 11, No. 46, 20.11.2019, p. 43781-43788.

Research output: Contribution to journalArticleResearchpeer-review

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T1 - Confinement-induced giant spin-orbit-coupled magnetic moment of Co nanoclusters in TiO2 films

AU - Ding, Xiang

AU - Cui, Xiangyuan

AU - Xiao, Chi

AU - Luo, Xi

AU - Bao, Nina

AU - Rusydi, Andrivo

AU - Yu, Xiaojiang

AU - Lu, Zunming

AU - Du, Yonghua

AU - Guan, Xinwei

AU - Tseng, Li-Ting

AU - Lee, Wai Tung

AU - Ahmed, Sohail

AU - Zheng, Rongkun

AU - Liu, Tao

AU - Wu, Tom

AU - Ding, Jun

AU - Suzuki, Kiyonori

AU - Lauter, Valeria

AU - Vinu, Ajayan

AU - Ringer, Simon P.

AU - Yi, Jia Bao

PY - 2019/11/20

Y1 - 2019/11/20

N2 - High magnetization materials are in great demand for the fabrication of advanced multifunctional magnetic devices. Notwithstanding this demand, the development of new materials with these attributes has been relatively slow. In this work, we propose a new strategy to achieve high magnetic moments above room temperature. Our material engineering approach invoked the embedding of magnetic nanoclusters in an oxide matrix. By precisely controlling pulsed laser deposition parameters, Co nanoclusters are formed in a 5 at % Co-TiO2 film. The presence of these nanoclusters was confirmed using transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray absorption fine structure. The film exhibits a very high saturation magnetization of 99 emu/cm3. Detailed studies using X-ray magnetic circular dichroism confirm that Co has an enhanced magnetic moment of 3.5 μB/atom, while the Ti and O also contribute to the magnetic moments. First-principles calculations supported our hypothesis that the metallic Co nanoclusters surrounded by a TiO2 matrix can exhibit both large spin and orbital moments. Moreover, a quantum confinement effect results in a high Curie temperature for the embedded Co nanoclusters. These findings reveal that 1-2 nm nanoclusters that are quantum confined can exhibit very large magnetic moments above room temperature, representing a promising advance for the design of new high magnetization materials.

AB - High magnetization materials are in great demand for the fabrication of advanced multifunctional magnetic devices. Notwithstanding this demand, the development of new materials with these attributes has been relatively slow. In this work, we propose a new strategy to achieve high magnetic moments above room temperature. Our material engineering approach invoked the embedding of magnetic nanoclusters in an oxide matrix. By precisely controlling pulsed laser deposition parameters, Co nanoclusters are formed in a 5 at % Co-TiO2 film. The presence of these nanoclusters was confirmed using transmission electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray absorption fine structure. The film exhibits a very high saturation magnetization of 99 emu/cm3. Detailed studies using X-ray magnetic circular dichroism confirm that Co has an enhanced magnetic moment of 3.5 μB/atom, while the Ti and O also contribute to the magnetic moments. First-principles calculations supported our hypothesis that the metallic Co nanoclusters surrounded by a TiO2 matrix can exhibit both large spin and orbital moments. Moreover, a quantum confinement effect results in a high Curie temperature for the embedded Co nanoclusters. These findings reveal that 1-2 nm nanoclusters that are quantum confined can exhibit very large magnetic moments above room temperature, representing a promising advance for the design of new high magnetization materials.

KW - enhanced magnetic moment

KW - ferromagnetism

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