Compounds containing λ3,σ2-Sb=C bonds: Synthesis and structural characterisation of the first stiba-enol, Mes*C(O)Sb=C(OH)Mes* (Mes* = C6H2But3-2,4,6) and a 2,3-distibabutadiene, {Mes(Me3SiO)C=Sb}2 (Mes = C6H2Me3-2,4,6)

Cameron Jones; Jonathan W. Steed; Rjan C. Thomas

doi:10.1039/a902791b

Compounds containing λ³,σ²-Sb=C bonds: Synthesis and structural characterisation of the first stiba-enol, MesC(O)Sb=C(OH)Mes (Mes* = C₆H₂Bu^t₃-2,4,6) and a 2,3-distibabutadiene, {Mes(Me₃SiO)C=Sb}₂ (Mes = C₆H₂Me₃-2,4,6)

Cameron Jones, Jonathan W. Steed, Rjan C. Thomas

Research output: Contribution to journal › Article › Research › peer-review

28 Citations (Scopus)

Abstract

The reactions of [Li{Sb(SiMe₃)₂}] with RCOCl, R = C₆H₂Bu^t₃-2,4,6 (Mes*) or C₆H₂Me₃-2,4,6 (Mes), afford mixtures of the 2,3-distibabutadienes, {R(Me₃SiO)C=Sb}₂, and the 2-stiba-1,3-dionatolithium complexes, [Li{OC(R)-SbC(R)O}(DME)_n], n = 1 or 0.5, the latter of which (R = Mes*) can be protonated to give the first stiba-enol, Mes*C(O)Sb=C(OH)Mes*, which has been structurally characterised.

Original language	English
Pages (from-to)	1541-1542
Number of pages	2
Journal	Dalton
Issue number	10
DOIs	https://doi.org/10.1039/a902791b
Publication status	Published - 21 May 1999
Externally published	Yes

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10.1039/a902791b

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title = "Compounds containing λ3,σ2-Sb=C bonds: Synthesis and structural characterisation of the first stiba-enol, Mes*C(O)Sb=C(OH)Mes* (Mes* = C6H2But3-2,4,6) and a 2,3-distibabutadiene, {Mes(Me3SiO)C=Sb}2 (Mes = C6H2Me3-2,4,6)",

abstract = "The reactions of [Li{Sb(SiMe3)2}] with RCOCl, R = C6H2But3-2,4,6 (Mes*) or C6H2Me3-2,4,6 (Mes), afford mixtures of the 2,3-distibabutadienes, {R(Me3SiO)C=Sb}2, and the 2-stiba-1,3-dionatolithium complexes, [Li{OC(R)-SbC(R)O}(DME)n], n = 1 or 0.5, the latter of which (R = Mes*) can be protonated to give the first stiba-enol, Mes*C(O)Sb=C(OH)Mes*, which has been structurally characterised.",

author = "Cameron Jones and Steed, {Jonathan W.} and Thomas, {Rjan C.}",

year = "1999",

month = may,

day = "21",

doi = "10.1039/a902791b",

language = "English",

pages = "1541--1542",

journal = "Dalton",

issn = "0300-9246",

publisher = "The Royal Society of Chemistry",

number = "10",

}

Compounds containing λ³,σ²-Sb=C bonds: Synthesis and structural characterisation of the first stiba-enol, Mes*C(O)Sb=C(OH)Mes* (Mes* = C₆H₂Bu^t₃-2,4,6) and a 2,3-distibabutadiene, {Mes(Me₃SiO)C=Sb}₂ (Mes = C₆H₂Me₃-2,4,6). / Jones, Cameron; Steed, Jonathan W.; Thomas, Rjan C.
In: Dalton, No. 10, 21.05.1999, p. 1541-1542.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Compounds containing λ3,σ2-Sb=C bonds

T2 - Synthesis and structural characterisation of the first stiba-enol, Mes*C(O)Sb=C(OH)Mes* (Mes* = C6H2But3-2,4,6) and a 2,3-distibabutadiene, {Mes(Me3SiO)C=Sb}2 (Mes = C6H2Me3-2,4,6)

AU - Jones, Cameron

AU - Steed, Jonathan W.

AU - Thomas, Rjan C.

PY - 1999/5/21

Y1 - 1999/5/21

N2 - The reactions of [Li{Sb(SiMe3)2}] with RCOCl, R = C6H2But3-2,4,6 (Mes*) or C6H2Me3-2,4,6 (Mes), afford mixtures of the 2,3-distibabutadienes, {R(Me3SiO)C=Sb}2, and the 2-stiba-1,3-dionatolithium complexes, [Li{OC(R)-SbC(R)O}(DME)n], n = 1 or 0.5, the latter of which (R = Mes*) can be protonated to give the first stiba-enol, Mes*C(O)Sb=C(OH)Mes*, which has been structurally characterised.

AB - The reactions of [Li{Sb(SiMe3)2}] with RCOCl, R = C6H2But3-2,4,6 (Mes*) or C6H2Me3-2,4,6 (Mes), afford mixtures of the 2,3-distibabutadienes, {R(Me3SiO)C=Sb}2, and the 2-stiba-1,3-dionatolithium complexes, [Li{OC(R)-SbC(R)O}(DME)n], n = 1 or 0.5, the latter of which (R = Mes*) can be protonated to give the first stiba-enol, Mes*C(O)Sb=C(OH)Mes*, which has been structurally characterised.

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U2 - 10.1039/a902791b

DO - 10.1039/a902791b

M3 - Article

AN - SCOPUS:33748659525

SN - 0300-9246

SP - 1541

EP - 1542

JO - Dalton

JF - Dalton

IS - 10

ER -

Compounds containing λ3,σ2-Sb=C bonds: Synthesis and structural characterisation of the first stiba-enol, Mes*C(O)Sb=C(OH)Mes* (Mes* = C6H2But3-2,4,6) and a 2,3-distibabutadiene, {Mes(Me3SiO)C=Sb}2 (Mes = C6H2Me3-2,4,6)

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Compounds containing λ³,σ²-Sb=C bonds: Synthesis and structural characterisation of the first stiba-enol, MesC(O)Sb=C(OH)Mes (Mes* = C₆H₂Bu^t₃-2,4,6) and a 2,3-distibabutadiene, {Mes(Me₃SiO)C=Sb}₂ (Mes = C₆H₂Me₃-2,4,6)