Complex multiblock bottle-brush architectures by RAFT polymerization

Andrew Kerr; Matthias Hartlieb; Joaquin Sanchis; Timothy Smith; Sébastien Perrier

doi:10.1039/c7cc07241d

Complex multiblock bottle-brush architectures by RAFT polymerization

Andrew Kerr, Matthias Hartlieb, Joaquin Sanchis, Timothy Smith, Sébastien Perrier

Drug Delivery Disposition & Dynamics

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52 Citations (Scopus)

Abstract

The combination of the reversible addition fragmentation chain transfer (RAFT) polymerization R-group grafting from approach and RAFT one-pot acrylamide multiblock methodology is used to synthesise complex bottle-brush architectures. This is demonstrated for block copolymer grafted side chains and the insertion of ungrafted blocks into the backbone to yield multi-segmented bottle-brushes.

Original language	English
Pages (from-to)	11901-11904
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	87
DOIs	https://doi.org/10.1039/c7cc07241d
Publication status	Published - 2017

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10.1039/c7cc07241d

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abstract = "The combination of the reversible addition fragmentation chain transfer (RAFT) polymerization R-group grafting from approach and RAFT one-pot acrylamide multiblock methodology is used to synthesise complex bottle-brush architectures. This is demonstrated for block copolymer grafted side chains and the insertion of ungrafted blocks into the backbone to yield multi-segmented bottle-brushes.",

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AU - Sanchis, Joaquin

AU - Smith, Timothy

AU - Perrier, Sébastien

PY - 2017

Y1 - 2017

N2 - The combination of the reversible addition fragmentation chain transfer (RAFT) polymerization R-group grafting from approach and RAFT one-pot acrylamide multiblock methodology is used to synthesise complex bottle-brush architectures. This is demonstrated for block copolymer grafted side chains and the insertion of ungrafted blocks into the backbone to yield multi-segmented bottle-brushes.

AB - The combination of the reversible addition fragmentation chain transfer (RAFT) polymerization R-group grafting from approach and RAFT one-pot acrylamide multiblock methodology is used to synthesise complex bottle-brush architectures. This is demonstrated for block copolymer grafted side chains and the insertion of ungrafted blocks into the backbone to yield multi-segmented bottle-brushes.

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U2 - 10.1039/c7cc07241d

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VL - 53

SP - 11901

EP - 11904

JO - Chemical Communications

JF - Chemical Communications

IS - 87

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Complex multiblock bottle-brush architectures by RAFT polymerization

Abstract

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