Comparison of coal liquefaction yields from two different reactor systems: The importance of loading and mixing in determining batch autoclave results

Peter J. Redlich, Chris K.J. Hulston, Masahide Sasaki, W. Roy Jackson, Frank P. Larkins, Marc Marshall

Research output: Contribution to journalArticleResearchpeer-review

8 Citations (Scopus)

Abstract

High conversions in Ni-Mo-and NaAlO2-Ni-Mo-catalysed no-solvent hydrogenation of a low-rank coal were obtained in a 35 mL reactor (1 g coal charge) heated in a horizontal position with vertical agitation. Much lower conversions were obtained in a 55 mL reactor (3 g coal charge) heated in a vertical position with a stirrer; however, the favourable effect of NaAlO2 addition in giving high oil/asphaltene ratios was preserved. The effects of addition of solvent (tetralin and decalin) and varying the coal loading in the 55 mL autoclave showed the importance of good accessibility of the reactant gas to the coal particles.

Original languageEnglish
Pages (from-to)1467-1470
Number of pages4
JournalFuel
Volume75
Issue number12
DOIs
Publication statusPublished - 1 Jan 1996

Keywords

  • Coal liquefaction: Mass transfer
  • Reactor type

Cite this