Cobalt-Catalyzed Chain Transfer Polymerization: A Review

S. Slavin; K. McEwan; D. M. Haddleton

doi:10.1016/B978-0-444-53349-4.00068-6

Cobalt-Catalyzed Chain Transfer Polymerization: A Review

S. Slavin
, K. McEwan
, D. M. Haddleton

Research output: Chapter in Book/Report/Conference proceeding › Chapter (Book) › Research › peer-review

31 Citations (Scopus)

Abstract

This chapter discusses cobalt-catalyzed catalytic chain transfer polymerization (CCTP). The use of Co(II) macrocycles as catalytic chain transfer (CCT) agents in free radical polymerization is a convenient method for the synthesis of low-molecular-weight polymers with vinyl end-functionality. To introduce the reader to the subject, the history and patent literature are described followed by in-depth sections on the catalytic mechanism, catalysts employed, monomers, reaction conditions, and CCT applications. An up-to-date review is provided covering all sections.

Original language	English
Title of host publication	Polymer Science
Subtitle of host publication	A Comprehensive Reference, 10 Volume Set
Publisher	Elsevier
Pages	249-275
Number of pages	27
Volume	3
ISBN (Print)	9780080878621
DOIs	https://doi.org/10.1016/B978-0-444-53349-4.00068-6
Publication status	Published - 2012
Externally published	Yes

Keywords

Catalytic
Chain transfer
Cobalt emulsion
Free radical
Macromonomers
Methacrylates
Polymerization
Porphyrin
Transition metal complexes

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10.1016/B978-0-444-53349-4.00068-6

Cite this

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title = "Cobalt-Catalyzed Chain Transfer Polymerization: A Review",

abstract = "This chapter discusses cobalt-catalyzed catalytic chain transfer polymerization (CCTP). The use of Co(II) macrocycles as catalytic chain transfer (CCT) agents in free radical polymerization is a convenient method for the synthesis of low-molecular-weight polymers with vinyl end-functionality. To introduce the reader to the subject, the history and patent literature are described followed by in-depth sections on the catalytic mechanism, catalysts employed, monomers, reaction conditions, and CCT applications. An up-to-date review is provided covering all sections.",

keywords = "Catalytic, Chain transfer, Cobalt emulsion, Free radical, Macromonomers, Methacrylates, Polymerization, Porphyrin, Transition metal complexes",

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TY - CHAP

T1 - Cobalt-Catalyzed Chain Transfer Polymerization

T2 - A Review

AU - Slavin, S.

AU - McEwan, K.

AU - Haddleton, D. M.

PY - 2012

Y1 - 2012

N2 - This chapter discusses cobalt-catalyzed catalytic chain transfer polymerization (CCTP). The use of Co(II) macrocycles as catalytic chain transfer (CCT) agents in free radical polymerization is a convenient method for the synthesis of low-molecular-weight polymers with vinyl end-functionality. To introduce the reader to the subject, the history and patent literature are described followed by in-depth sections on the catalytic mechanism, catalysts employed, monomers, reaction conditions, and CCT applications. An up-to-date review is provided covering all sections.

AB - This chapter discusses cobalt-catalyzed catalytic chain transfer polymerization (CCTP). The use of Co(II) macrocycles as catalytic chain transfer (CCT) agents in free radical polymerization is a convenient method for the synthesis of low-molecular-weight polymers with vinyl end-functionality. To introduce the reader to the subject, the history and patent literature are described followed by in-depth sections on the catalytic mechanism, catalysts employed, monomers, reaction conditions, and CCT applications. An up-to-date review is provided covering all sections.

KW - Catalytic

KW - Chain transfer

KW - Cobalt emulsion

KW - Free radical

KW - Macromonomers

KW - Methacrylates

KW - Polymerization

KW - Porphyrin

KW - Transition metal complexes

UR - https://www.scopus.com/pages/publications/84865124087

U2 - 10.1016/B978-0-444-53349-4.00068-6

DO - 10.1016/B978-0-444-53349-4.00068-6

M3 - Chapter (Book)

AN - SCOPUS:84865124087

SN - 9780080878621

VL - 3

SP - 249

EP - 275

BT - Polymer Science

PB - Elsevier

ER -

Cobalt-Catalyzed Chain Transfer Polymerization: A Review

Abstract

Keywords

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