Co-ordinative activation of phosphaalkynes: Methyl neopentylidene phosphorane complexes of ruthenium(II); crystal structure of [Ru(MeP=CHBut)Cl(I)(CO)(PPh3)2]

Robin B. Bedford, Anthony F. Hill, Cameron Jones, Andrew J.P. White, James D.E.T. Wilton-Ely

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Abstract

The reactions of [Ru(P=CHBut)Cl(CA)(PPh3)2] (A = O or S) with iodomethane provided the phosphaalkene complexes [Ru(PMe=CHBut)Cl(I)(CA)(PPh3)2] (I trans to phosphaalkene), with one example (A = O) having been crystallographically characterised.

Original languageEnglish
Pages (from-to)139-140
Number of pages2
JournalDalton
Issue number2
DOIs
Publication statusPublished - 21 Jan 1997
Externally publishedYes

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