Chromatographic parameters derived for the non-linear response of a flame photometric detector

P. J. Marriott, T. J. Cardwell

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6 Citations (Scopus)

Abstract

A mathematical derivation of efficiency and resolution equations for use in conjunction with flame photometric detection of sulphur compounds is presented. These equations are similar to those for linear detection apart from the incorporation of the exponential response factor, n, in the denominator of the respective expressions for non-linear detection. The latter equations reduce to those usually recognised for linear detection if the value n=1 is substituted. Equating the column efficiency equations for linear and non-linear detection permits direct determination of the value of n.

Original languageEnglish
Pages (from-to)279-284
Number of pages6
JournalChromatographia
Volume14
Issue number5
DOIs
Publication statusPublished - 1 May 1981
Externally publishedYes

Keywords

  • Flame photometric detector
  • Non-linear detection
  • Peak widths
  • Response factor
  • Sulphur mode

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